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SrCo0.4Fe0.4Zr0.1Y0.1O3-δ, A new CO2 tolerant cathode for proton-conducting solid oxide fuel cells

Author

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  • Lv, Xiuqing
  • Chen, Huili
  • Zhou, Wei
  • Li, Si-Dian
  • Cheng, Fangqin
  • Shao, Zongping

Abstract

CO2 poisoning is not a negligible issue for SrCoO3-δ based materials, which limits their application as cathodes for solid oxide fuel cells (SOFCs). In this paper, iron, zirconium, and yttrium were co-doped into SrCoO3-δ to form a structurally stable cubic perovskite material, SrCo0.4Fe0.4Zr0.1Y0.1O3-δ (SCFZY). The CO2 adsorption-desorption on SCFZY was studied via X-ray diffraction and CO2 temperature-programmed desorption. The polarization resistance of the symmetric cell SCFZY|BaZr0.1Ce0.7Y0.1Yb0.1O3-δ (BZCYYb)|SCFZY was tested in air containing 10 vol% CO2 to evaluate the SCFZY's CO2-tolerance as a SOFCs cathode. When applied as a SOFCs cathode in a cell with a proton-conducting electrolyte BZCYYb, SCFZY showed significant CO2-tolerance. The single-cell NiO-BZCYYb|BZCYYb|BZCYYb-SCFZY showed an output with a maximum power density of 679 mW cm−2 at 700 °C and good durability of 500 h. The SCFZY cathode also displayed better CO2-tolerance than the Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) cathode for IT- SOFCs.

Suggested Citation

  • Lv, Xiuqing & Chen, Huili & Zhou, Wei & Li, Si-Dian & Cheng, Fangqin & Shao, Zongping, 2022. "SrCo0.4Fe0.4Zr0.1Y0.1O3-δ, A new CO2 tolerant cathode for proton-conducting solid oxide fuel cells," Renewable Energy, Elsevier, vol. 185(C), pages 8-16.
    • Handle: RePEc:eee:renene:v:185:y:2022:i:c:p:8-16
    DOI: 10.1016/j.renene.2021.12.030
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    References listed on IDEAS

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    1. Zongping Shao & Sossina M. Haile, 2004. "A high-performance cathode for the next generation of solid-oxide fuel cells," Nature, Nature, vol. 431(7005), pages 170-173, September.
    2. Sharaf, Omar Z. & Orhan, Mehmet F., 2014. "An overview of fuel cell technology: Fundamentals and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 810-853.
    3. Cascos, V. & Fernández-Díaz, M.T. & Alonso, J.A., 2019. "Structural and electrical characterization of the novel SrCo1-xTixO3–δ (x = 0.05, 0.1 and 0.15) perovskites: Evaluation as cathode materials in solid oxide fuel cells," Renewable Energy, Elsevier, vol. 133(C), pages 205-215.
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