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Impact of high soot-loaded and regenerated diesel particulate filters on the emissions of persistent organic pollutants from a diesel engine fueled with waste cooking oil-based biodiesel

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  • Chen, Chia-Yang
  • Lee, Wen-Jhy
  • Wang, Lin-Chi
  • Chang, Yu-Cheng
  • Yang, Hsi-Hsien
  • Young, Li-Hao
  • Lu, Jau-Huai
  • Tsai, Ying I.
  • Cheng, Man-Ting
  • Mwangi, John Kennedy

Abstract

This study evaluated the impact on persistent organic pollutant (POP) emissions from a diesel engine when deploying a diesel oxidation catalyst (DOC) combined with an uncatalyzed diesel particulate filter (DPF), as well as fueling with conventional diesel (B2) and waste cooking oil-based (WCO-based) biodiesel blends (B10 and B20). When the engine was fueled with WCO-based biodiesel blends (B10 and B20) in combination with deploying DOC+A-DPF, their levels of the chlorine and potassium contents could not stimulate the formation of chlorinated POPs (PCDD/Fs and PCBs), although previous studies had warned that happened on diesel engines fueled with biodiesel and deployed with iron-catalyzed DPFs. In contrast, the WCO-based biodiesel with a lower aromatic content reduced the precursors for POP formation, and its higher oxygen content compared to diesel promoted more complete combustion, and thus using WCO-based biodiesel could reduce both PM2.5 and POP emissions from diesel engines. This study also evaluated the impact of DPF conditions on the POP emissions from a diesel engine; that is, the difference in POP emissions before and just after the regeneration of the DPF. In comparison to the high soot-loaded DPF scenario, the regeneration of the DPF can drastically reduce the formation potential of POPs in the DPFs. An approach was developed to correct the effects of sampling artifacts on the partitioning of gas- and particle-phase POPs in the exhaust. The gas-phase POPs are highly dominant (89.7–100%) in the raw exhausts of diesel engines, indicating that the formation mechanism of POPs in diesel engines is mainly through homogeneous gas-phase formation, rather than de novo synthesis.

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  • Chen, Chia-Yang & Lee, Wen-Jhy & Wang, Lin-Chi & Chang, Yu-Cheng & Yang, Hsi-Hsien & Young, Li-Hao & Lu, Jau-Huai & Tsai, Ying I. & Cheng, Man-Ting & Mwangi, John Kennedy, 2017. "Impact of high soot-loaded and regenerated diesel particulate filters on the emissions of persistent organic pollutants from a diesel engine fueled with waste cooking oil-based biodiesel," Applied Energy, Elsevier, vol. 191(C), pages 35-43.
  • Handle: RePEc:eee:appene:v:191:y:2017:i:c:p:35-43
    DOI: 10.1016/j.apenergy.2017.01.046
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    References listed on IDEAS

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    2. Ferrari, A. & Novara, C. & Paolucci, E. & Vento, O. & Violante, M. & Zhang, T., 2018. "Design and rapid prototyping of a closed-loop control strategy of the injected mass for the reduction of CO2, combustion noise and pollutant emissions in diesel engines," Applied Energy, Elsevier, vol. 232(C), pages 358-367.
    3. Zhao, Feiyang & Yang, Wenming & Yu, Wenbin & Li, Han & Sim, Yu Yun & Liu, Teng & Tay, Kun Lin, 2018. "Numerical study of soot particles from low temperature combustion of engine fueled with diesel fuel and unsaturation biodiesel fuels," Applied Energy, Elsevier, vol. 211(C), pages 187-193.
    4. Chuepeng, Sathaporn & Komintarachat, Cholada, 2018. "Interesterification optimization of waste cooking oil and ethyl acetate over homogeneous catalyst for biofuel production with engine validation," Applied Energy, Elsevier, vol. 232(C), pages 728-739.
    5. Boopathi, D. & Thiyagarajan, S. & Edwin Geo, V. & Madhankumar, S. & Gheith, R., 2018. "Effect of geraniol on performance, emission and combustion characteristics of CI engine fuelled with gutter oil obtained from different sources," Energy, Elsevier, vol. 157(C), pages 391-401.
    6. Zhao, Xiaohuan & Zuo, Hongyan & Jia, Guohai, 2022. "Effect analysis on pressure sensitivity performance of diesel particulate filter for heavy-duty truck diesel engine by the nonlinear soot regeneration combustion pressure model," Energy, Elsevier, vol. 257(C).
    7. Zhang, Jun & Wong, Victor W. & Shuai, Shijin & Chen, Yu & Sappok, Alexander, 2018. "Quantitative estimation of the impact of ash accumulation on diesel particulate filter related fuel penalty for a typical modern on-road heavy-duty diesel engine," Applied Energy, Elsevier, vol. 229(C), pages 1010-1023.

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