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Effects of gaseous ammonia direct injection on performance characteristics of a spark-ignition engine

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  • Ryu, Kyunghyun
  • Zacharakis-Jutz, George E.
  • Kong, Song-Charng

Abstract

The effects of direct injection of gaseous ammonia on the combustion characteristics and exhaust emissions of a spark-ignition engine were investigated. Port-injection gasoline was used to enhance the burning of ammonia that was directly injected into the engine cylinder. Appropriate direct injection strategies were developed to allow ammonia to be used in spark-ignition engines without sacrifice of volumetric efficiency. Experimental results show that with gasoline providing the baseline power of 0.6kW, total engine power could increase to 2.7kW when the injection timing of ammonia was advanced to 370 BTDC with injection duration of 22 ms. Engine performance with use of gasoline–ammonia was compared to that with gasoline alone. For operations using gasoline–ammonia, with baseline power from gasoline at 0.6kW the appropriate ammonia injection timing was found to range from 320 to 370 BTDC for producing 1.5–2.7kW. The peak pressures were slightly lower than those using gasoline alone because of the lower flame of ammonia, resulting in reduction of cylinder pressure. The brake specific energy consumption (BSEC) with gasoline–ammonia was very similar to that with gasoline alone. Ammonia direct injection caused slight reductions of BSCO for all the loads studied but significantly increased BSHC because of the reduced combustion temperature of ammonia combustion. The use of ammonia resulted in increased NOx emissions because of formation of fuel NOx. Ammonia slip was also detected in the engine exhaust because of incomplete combustion.

Suggested Citation

  • Ryu, Kyunghyun & Zacharakis-Jutz, George E. & Kong, Song-Charng, 2014. "Effects of gaseous ammonia direct injection on performance characteristics of a spark-ignition engine," Applied Energy, Elsevier, vol. 116(C), pages 206-215.
  • Handle: RePEc:eee:appene:v:116:y:2014:i:c:p:206-215
    DOI: 10.1016/j.apenergy.2013.11.067
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    9. Li, Jun & Huang, Hongyu & Kobayashi, Noriyuki & He, Zhaohong & Osaka, Yugo & Zeng, Tao, 2015. "Numerical study on effect of oxygen content in combustion air on ammonia combustion," Energy, Elsevier, vol. 93(P2), pages 2053-2068.
    10. Ezzat, M.F & Dincer, I., 2018. "Development and assessment of a new hybrid vehicle with ammonia and hydrogen," Applied Energy, Elsevier, vol. 219(C), pages 226-239.
    11. Muhammad Heikal Hasan & Teuku Meurah Indra Mahlia & M. Mofijur & I.M. Rizwanul Fattah & Fitri Handayani & Hwai Chyuan Ong & A. S. Silitonga, 2021. "A Comprehensive Review on the Recent Development of Ammonia as a Renewable Energy Carrier," Energies, MDPI, vol. 14(13), pages 1-32, June.
    12. Mosevitzky, Bar & Azoulay, Rotem & Naamat, Lilach & Shter, Gennady E. & Grader, Gideon S., 2018. "Effects of water content and diluent pressure on the ignition of aqueous ammonia/ammonium nitrate and urea/ammonium nitrate fuels," Applied Energy, Elsevier, vol. 224(C), pages 300-308.
    13. Yapicioglu, Arda & Dincer, Ibrahim, 2019. "A review on clean ammonia as a potential fuel for power generators," Renewable and Sustainable Energy Reviews, Elsevier, vol. 103(C), pages 96-108.
    14. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
    15. Fengshuo He & Xiumin Yu & Yaodong Du & Zhen Shang & Zezhou Guo & Guanting Li & Decheng Li, 2019. "Inner Selective Non-Catalytic Reduction Strategy for Nitrogen Oxides Abatement: Investigation of Ammonia Aqueous Solution Direct Injection with an SI Engine Model," Energies, MDPI, vol. 12(14), pages 1-18, July.
    16. Li, Jun & Huang, Hongyu & Kobayashi, Noriyuki & Wang, Chenguang & Yuan, Haoran, 2017. "Numerical study on laminar burning velocity and ignition delay time of ammonia flame with hydrogen addition," Energy, Elsevier, vol. 126(C), pages 796-809.
    17. Lu, Zhen & Ye, Jianpeng & Gui, Yong & Lu, Tianlong & Shi, Lei & An, Yanzhao & Wang, Tianyou, 2023. "Numerical study of the compression ignition of ammonia in a two-stroke marine engine by using HTCGR strategy," Energy, Elsevier, vol. 276(C).
    18. Ahmed T. Khalil & Dimitris M. Manias & Efstathios-Al. Tingas & Dimitrios C. Kyritsis & Dimitris A. Goussis, 2019. "Algorithmic Analysis of Chemical Dynamics of the Autoignition of NH 3 –H 2 O 2 /Air Mixtures," Energies, MDPI, vol. 12(23), pages 1-14, November.

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