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Highly active platinum electrocatalyst towards oxygen reduction reaction in renewable energy generations of proton exchange membrane fuel cells

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  • Wang, Yang
  • Luo, Hui
  • Li, Guang
  • Jiang, Jianming

Abstract

Reducing platinum usage and increasing its electrocatalytic durability are the key issues for the successful application of PEMFC. Fabricating platinum into specific morphologic structure and combining with the superior support is one of effective resolutions. In this paper, porous carbon nanofibers supported platinum nanowires (PtNW/PCNF) were synthesized via a simple and inexpensive template-free methodology and used oxygen reduction reaction (ORR) electrocatalyst. As a comparison, Pt nanowires supported on commercial carbon black (PtNW/Vulcan) was also prepared in the same condition. High-resolution transmission electron microscopy (TEM) shows that the single-crystal Pt nanowires were successfully grown on the support. The electrocatalytic activity and stability of the resultant catalysts along with the commercial one (JM20) were investigated by using cyclic voltammetry (CV) and liner sweep voltammetry (LSV) with a rotating disk electrode (RDE). As a result, the PtNW/PCNF exhibited much enhanced electrocatalytic activity and stability compared with the PtNW/Vulcan and JM20. The mass activity (at 0.80V vs. RHE) of the PtNW/PCNF is about 1.7 and 2.3 times higher than that of PtNW/Vulcan and JM20, respectively. The remnant ECSA of the PtNW/PCNF after 1000cycles was about 32% compared with the initial one whereas JM20 and PtNW/Vulcan retained only 10% and 23%. Furthermore, after ADT test for the three electrocatalysts, PtNW/PCNF lost 51mV in half-wave potential, significantly better than the 150mV half-wave potential loss for PtNW/Vulcan and almost complete loss of performance for commercial JM20. These results indicate controlled growth of Pt nanowires as a potential choice for conventional Pt nanoparticles and PCNFs a promising candidate as catalyst supports for the enhancement of PEMFC performance.

Suggested Citation

  • Wang, Yang & Luo, Hui & Li, Guang & Jiang, Jianming, 2016. "Highly active platinum electrocatalyst towards oxygen reduction reaction in renewable energy generations of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 173(C), pages 59-66.
    • Handle: RePEc:eee:appene:v:173:y:2016:i:c:p:59-66
    DOI: 10.1016/j.apenergy.2016.04.019
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    References listed on IDEAS

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    1. Mark K. Debe, 2012. "Electrocatalyst approaches and challenges for automotive fuel cells," Nature, Nature, vol. 486(7401), pages 43-51, June.
    2. Pei, Pucheng & Chen, Huicui, 2014. "Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review," Applied Energy, Elsevier, vol. 125(C), pages 60-75.
    3. Cho, Junhyun & Park, Jaeman & Oh, Hwanyeong & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2013. "Analysis of the transient response and durability characteristics of a proton exchange membrane fuel cell with different micro-porous layer penetration thicknesses," Applied Energy, Elsevier, vol. 111(C), pages 300-309.
    4. Trongchuankij, Wiruyn & Pruksathorn, Kejvalee & Hunsom, Mali, 2011. "Preparation of a high performance Pt-Co/C electrocatalyst for oxygen reduction in PEM fuel cell via a combined process of impregnation and seeding," Applied Energy, Elsevier, vol. 88(3), pages 974-980, March.
    5. Jung, Guo-Bin & Tzeng, Wei-Jen & Jao, Ting-Chu & Liu, Yu-Hsu & Yeh, Chia-Chen, 2013. "Investigation of porous carbon and carbon nanotube layer for proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 101(C), pages 457-464.
    6. Oh, Hwanyeong & Park, Jaeman & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2015. "Effects of pore size gradient in the substrate of a gas diffusion layer on the performance of a proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 149(C), pages 186-193.
    7. Zhang, Lei & Kim, Jenny & Zhang, Jiujun & Nan, Feihong & Gauquelin, Nicolas & Botton, Gianluigi A. & He, Ping & Bashyam, Rajesh & Knights, Shanna, 2013. "Ti4O7 supported Ru@Pt core–shell catalyst for CO-tolerance in PEM fuel cell hydrogen oxidation reaction," Applied Energy, Elsevier, vol. 103(C), pages 507-513.
    8. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
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    2. Zhang, Jingjing & Wang, Biao & Jin, Junhong & Yang, Shenglin & Li, Guang, 2022. "A review of the microporous layer in proton exchange membrane fuel cells: Materials and structural designs based on water transport mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    3. Zhong, Kengqiang & Li, Meng & Yang, Yue & Zhang, Hongguo & Zhang, Bopeng & Tang, Jinfeng & Yan, Jia & Su, Minhua & Yang, Zhiquan, 2019. "Nitrogen-doped biochar derived from watermelon rind as oxygen reduction catalyst in air cathode microbial fuel cells," Applied Energy, Elsevier, vol. 242(C), pages 516-525.
    4. Shahgaldi, Samaneh & Alaefour, Ibrahim & Li, Xianguo, 2018. "Impact of manufacturing processes on proton exchange membrane fuel cell performance," Applied Energy, Elsevier, vol. 225(C), pages 1022-1032.

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