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Shape stabilised phase change materials based on a high melt viscosity HDPE and paraffin waxes

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  • Mu, Mulan
  • Basheer, P.A.M.
  • Sha, Wei
  • Bai, Yun
  • McNally, Tony

Abstract

Shape stabilised phase change materials (SSPCMs) based on a high density poly(ethylene)(hv-HDPE) with high (H-PW, Tm=56–58°C) and low (L-PW, Tm=18–23°C) melting point paraffin waxes were readily prepared using twin-screw extrusion. The thermo-physical properties of these materials were assessed using a combination of techniques and their suitability for latent heat thermal energy storage (LHTES) assessed. The melt processing temperature (160°C) of the HDPE used was well below the onset of thermal decomposition of H-PW (220°C), but above that for L-PW (130°C), although the decomposition process extended over a range of 120°C and the residence time of L-PW in the extruder was <30s. The SSPCMs prepared had latent heats up to 89J/g and the enthalpy values for H-PW in the respective blends decreased with increasing H-PW loading, as a consequence of co-crystallisation of H-PW and hv-HDPE. Static and dynamic mechanical analysis confirmed both waxes have a plasticisation effect on this HDPE. Irrespective of the mode of deformation (tension, flexural, compression) modulus and stress decreased with increased wax loading in the blend, but the H-PW blends were mechanically superior to those with L-PW.

Suggested Citation

  • Mu, Mulan & Basheer, P.A.M. & Sha, Wei & Bai, Yun & McNally, Tony, 2016. "Shape stabilised phase change materials based on a high melt viscosity HDPE and paraffin waxes," Applied Energy, Elsevier, vol. 162(C), pages 68-82.
    • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:68-82
    DOI: 10.1016/j.apenergy.2015.10.030
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