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An organic group contribution approach to radiative efficiency estimation of organic working fluid

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  • Zhang, Xinxin
  • Kobayashi, Noriyuki
  • He, Maogang
  • Wang, Jingfu

Abstract

The ratification of the Montreal Protocol in 1987 and the Kyoto Protocol in 1997 mark an environment protection era of the development of organic working fluid. Ozone depletion potential (ODP) and global warming potential (GWP) are two most important indices for the quantitative comparison of organic working fluid. Nowadays, more and more attention has been paid to GWP. The calculation of GWP is an extremely complicated process which involves interactions between surface and atmosphere such as atmospheric radiative transfer and atmospheric chemical reactions. GWP of a substance is related to its atmospheric abundance and is a variable in itself. However, radiative efficiency is an intermediate parameter for GWP calculation and it is a constant value used to describe inherent property of a substance. In this paper, the group contribution method was adopted to estimate the radiative efficiency of the organic substance which contains more than one carbon atom. In most cases, the estimation value and the standard value are in a good agreement. The biggest estimation error occurs in the estimation of the radiative efficiency of fluorinated ethers due to its plenty of structure groups and its complicated structure compared with hydrocarbon. This estimation method can be used to predict the radiative efficiency of newly developed organic working fluids.

Suggested Citation

  • Zhang, Xinxin & Kobayashi, Noriyuki & He, Maogang & Wang, Jingfu, 2016. "An organic group contribution approach to radiative efficiency estimation of organic working fluid," Applied Energy, Elsevier, vol. 162(C), pages 1205-1210.
    • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1205-1210
    DOI: 10.1016/j.apenergy.2015.08.032
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    Cited by:

    1. Chen, Chonghui & Xing, Lingli & Su, Wen & Lin, Xinxing, 2023. "Performance prediction and design of CO2 mixtures with the PR-VDW model and molecular groups for the transcritical power cycle," Energy, Elsevier, vol. 282(C).
    2. Su, Wen & Zhao, Li & Deng, Shuai, 2017. "Simultaneous working fluids design and cycle optimization for Organic Rankine cycle using group contribution model," Applied Energy, Elsevier, vol. 202(C), pages 618-627.

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