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A numerical study on the effects of temperature and mass transfer in high temperature PEM fuel cells with ab-PBI membrane

Author

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  • Sun, Hong
  • Xie, Chen
  • Chen, Hao
  • Almheiri, Saif

Abstract

A two-dimensional, single-phase model is developed to study high temperature proton exchange membrane (HT-PEM) fuel cell with poly(2,5-benzimidazole) (ab-PBI) membrane. In this model, simulation region not only includes the cathode and anode, but also includes ab-PBI membrane; the continuity boundary condition at the interface between the catalyst layer (CL) and the gas diffusion layer (GDL) at each side of the cell is omitted by including the catalyst layers in the respective unified domains for the cathode and the anode. The flows, species, energy, current density are all coupled in the model. Experiments have been conducted to validate the proposed numerical simulations, and it is found that there is a good agreement between the modeling results and those obtained experimentally. By this simulation, not only the oxygen and water fraction distribution in the cathode, but also the temperature distribution and resistance distribution in the ab-PBI membrane are obtained, and the effects of the cell temperature, the porosity in the diffusion layer and its thickness on the current density are analyzed. The innovative researching results are that the temperature distribution is uneven in the ab-PBI membrane and its resistance is greatly affected by the operating temperature. Other results show that the increase of the cell temperature and the porosity in the diffusion layer, and the decrease of the diffusion layer thickness all improve the performance of HT-PEM fuel cells by promoting its internal mass transfer.

Suggested Citation

  • Sun, Hong & Xie, Chen & Chen, Hao & Almheiri, Saif, 2015. "A numerical study on the effects of temperature and mass transfer in high temperature PEM fuel cells with ab-PBI membrane," Applied Energy, Elsevier, vol. 160(C), pages 937-944.
    • Handle: RePEc:eee:appene:v:160:y:2015:i:c:p:937-944
    DOI: 10.1016/j.apenergy.2015.02.053
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    References listed on IDEAS

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    1. Kim, Jintae & Kim, Minjin & Kang, Taegon & Sohn, Young-Jun & Song, Taewon & Choi, Kyoung Hwan, 2014. "Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM (proton exchange membrane) fuel cells," Energy, Elsevier, vol. 66(C), pages 41-49.
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    2. Li, Yan & Shi, Yan & Mehio, Nada & Tan, Mingsheng & Wang, Zhiyong & Hu, Xiaohong & Chen, George Z. & Dai, Sheng & Jin, Xianbo, 2016. "More sustainable electricity generation in hot and dry fuel cells with a novel hybrid membrane of Nafion/nano-silica/hydroxyl ionic liquid," Applied Energy, Elsevier, vol. 175(C), pages 451-458.
    3. Ribeirinha, P. & Abdollahzadeh, M. & Sousa, J.M. & Boaventura, M. & Mendes, A., 2017. "Modelling of a high-temperature polymer electrolyte membrane fuel cell integrated with a methanol steam reformer cell," Applied Energy, Elsevier, vol. 202(C), pages 6-19.
    4. Thomas, Sobi & Vang, Jakob Rabjerg & Araya, Samuel Simon & Kær, Søren Knudsen, 2017. "Experimental study to distinguish the effects of methanol slip and water vapour on a high temperature PEM fuel cell at different operating conditions," Applied Energy, Elsevier, vol. 192(C), pages 422-436.
    5. Andújar, J.M. & Segura, F. & Isorna, F. & Calderón, A.J., 2018. "Comprehensive diagnosis methodology for faults detection and identification, and performance improvement of Air-Cooled Polymer Electrolyte Fuel Cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 193-207.
    6. Blal, Mohamed & Benatiallah, Ali & NeÇaibia, Ammar & Lachtar, Salah & Sahouane, Nordine & Belasri, Ahmed, 2019. "Contribution and investigation to compare models parameters of (PEMFC), comprehensives review of fuel cell models and their degradation," Energy, Elsevier, vol. 168(C), pages 182-199.
    7. Li, Zhongliang & Outbib, Rachid & Giurgea, Stefan & Hissel, Daniel & Jemei, Samir & Giraud, Alain & Rosini, Sebastien, 2016. "Online implementation of SVM based fault diagnosis strategy for PEMFC systems," Applied Energy, Elsevier, vol. 164(C), pages 284-293.
    8. Xiong, Kangning & Wu, Wei & Wang, Shuangfeng & Zhang, Lin, 2021. "Modeling, design, materials and fabrication of bipolar plates for proton exchange membrane fuel cell: A review," Applied Energy, Elsevier, vol. 301(C).
    9. Xie, Biao & Zhang, Hanyang & Huo, Wenming & Wang, Renfang & Zhu, Ying & Wu, Lizhen & Zhang, Guobin & Ni, Meng & Jiao, Kui, 2023. "Large-scale three-dimensional simulation of proton exchange membrane fuel cell considering detailed water transition mechanism," Applied Energy, Elsevier, vol. 331(C).
    10. Liu, Yongfeng & Fan, Lei & Pei, Pucheng & Yao, Shengzhuo & Wang, Fang, 2018. "Asymptotic analysis for the inlet relative humidity effects on the performance of proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 213(C), pages 573-584.
    11. Zhang, S. & Reimer, U. & Beale, S.B. & Lehnert, W. & Stolten, D., 2019. "Modeling polymer electrolyte fuel cells: A high precision analysis," Applied Energy, Elsevier, vol. 233, pages 1094-1103.
    12. Singdeo, Debanand & Dey, Tapobrata & Gaikwad, Shrihari & Andreasen, Søren Juhl & Ghosh, Prakash C., 2017. "A new modified-serpentine flow field for application in high temperature polymer electrolyte fuel cell," Applied Energy, Elsevier, vol. 195(C), pages 13-22.

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