IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v134y2014icp342-348.html
   My bibliography  Save this article

Direct methanol utilization in intermediate temperature liquid-tin anode solid oxide fuel cells

Author

Listed:
  • Hu, Boxun
  • Keane, Michael
  • Patil, Kailash
  • Mahapatra, Manoj K.
  • Pasaogullari, Ugur
  • Singh, Prabhakar

Abstract

Direct utilization of methanol in liquid tin anode solid oxide fuel cells has been experimentally demonstrated at 1023K. A Cu and SDC modified Sn anode solid oxide fuel cell had a maximum power density of 259.2mW/cm2 during operation on methanol. Carbon deposition was not observed in the Raman spectra of the post-test anodes. Electrochemical impedance spectroscopy indicated that gas conversion resistance increased when using methanol instead of hydrogen. The micro-channel architecture of the electrode mitigated the increase. Scanning electron microscopy images showed that addition of Cu and Sn improved wetting of Sn on YSZ and reduced anode polarization resistance. The anode gases were analyzed by mass spectroscopy and a mechanism for electrochemical oxidation of methanol has been proposed.

Suggested Citation

  • Hu, Boxun & Keane, Michael & Patil, Kailash & Mahapatra, Manoj K. & Pasaogullari, Ugur & Singh, Prabhakar, 2014. "Direct methanol utilization in intermediate temperature liquid-tin anode solid oxide fuel cells," Applied Energy, Elsevier, vol. 134(C), pages 342-348.
    • Handle: RePEc:eee:appene:v:134:y:2014:i:c:p:342-348
    DOI: 10.1016/j.apenergy.2014.08.030
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261914008332
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2014.08.030?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. McLarty, Dustin & Brouwer, Jack, 2014. "Poly-generating closed cathode fuel cell with carbon capture," Applied Energy, Elsevier, vol. 131(C), pages 108-116.
    2. Pruitt, Kristopher A. & Braun, Robert J. & Newman, Alexandra M., 2013. "Establishing conditions for the economic viability of fuel cell-based, combined heat and power distributed generation systems," Applied Energy, Elsevier, vol. 111(C), pages 904-920.
    3. Seungdoo Park & John M. Vohs & Raymond J. Gorte, 2000. "Direct oxidation of hydrocarbons in a solid-oxide fuel cell," Nature, Nature, vol. 404(6775), pages 265-267, March.
    4. Santin, Marco & Traverso, Alberto & Magistri, Loredana, 2009. "Liquid fuel utilization in SOFC hybrid systems," Applied Energy, Elsevier, vol. 86(10), pages 2204-2212, October.
    5. E. Perry Murray & T. Tsai & S. A. Barnett, 1999. "A direct-methane fuel cell with a ceria-based anode," Nature, Nature, vol. 400(6745), pages 649-651, August.
    6. Park, Sung Ku & Kim, Tong Seop & Sohn, Jeong L. & Lee, Young Duk, 2011. "An integrated power generation system combining solid oxide fuel cell and oxy-fuel combustion for high performance and CO2 capture," Applied Energy, Elsevier, vol. 88(4), pages 1187-1196, April.
    7. Hong, Wen-Tang & Yen, Tzu-Hsiang & Chung, Tsang-Dong & Huang, Cheng-Nan & Chen, Bao-Dong, 2011. "Efficiency analyses of ethanol-fueled solid oxide fuel cell power system," Applied Energy, Elsevier, vol. 88(11), pages 3990-3998.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gupta, Sapna & Adams, Joseph J. & Wilson, Jamie R. & Eddings, Eric G. & Mahapatra, Manoj K. & Singh, Prabhakar, 2016. "Performance and post-test characterization of an OTM system in an experimental coal gasifier," Applied Energy, Elsevier, vol. 165(C), pages 72-80.
    2. Xu, Han & Dang, Zheng, 2016. "Lattice Boltzmann modeling of carbon deposition in porous anode of a solid oxide fuel cell with internal reforming," Applied Energy, Elsevier, vol. 178(C), pages 294-307.
    3. Qu, Jifa & Wang, Wei & Chen, Yubo & Wang, Feng & Ran, Ran & Shao, Zongping, 2015. "Ethylene glycol as a new sustainable fuel for solid oxide fuel cells with conventional nickel-based anodes," Applied Energy, Elsevier, vol. 148(C), pages 1-9.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sariboğa, Vedat & Öksüzömer, Faruk, 2012. "The investigation of active Ni/YSZ interlayer for Cu-based direct-methane solid oxide fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 707-721.
    2. Yan, Min & Zeng, Min & Chen, Qiuyang & Wang, Qiuwang, 2012. "Numerical study on carbon deposition of SOFC with unsteady state variation of porosity," Applied Energy, Elsevier, vol. 97(C), pages 754-762.
    3. Chen, Daifen & Zeng, Qice & Su, Shichuan & Bi, Wuxi & Ren, Zhiqiang, 2013. "Geometric optimization of a 10-cell modular planar solid oxide fuel cell stack manifold," Applied Energy, Elsevier, vol. 112(C), pages 1100-1107.
    4. Azizi, Mohammad Ali & Brouwer, Jacob & Dunn-Rankin, Derek, 2016. "Analytical investigation of high temperature 1kW solid oxide fuel cell system feasibility in methane hydrate recovery and deep ocean power generation," Applied Energy, Elsevier, vol. 179(C), pages 909-928.
    5. Yu, Fangyong & Xiao, Jie & Zhang, Yapeng & Cai, Weizi & Xie, Yongmin & Yang, Naitao & Liu, Jiang & Liu, Meilin, 2019. "New insights into carbon deposition mechanism of nickel/yttrium-stabilized zirconia cermet from methane by in situ investigation," Applied Energy, Elsevier, vol. 256(C).
    6. Wee, Jung-Ho, 2011. "Molten carbonate fuel cell and gas turbine hybrid systems as distributed energy resources," Applied Energy, Elsevier, vol. 88(12), pages 4252-4263.
    7. Massimiliano Cimenti & Josephine M. Hill, 2009. "Direct Utilization of Liquid Fuels in SOFC for Portable Applications: Challenges for the Selection of Alternative Anodes," Energies, MDPI, vol. 2(2), pages 1-34, June.
    8. Mohamad Fairus Rabuni & Tao Li & Mohd Hafiz Dzarfan Othman & Faidzul Hakim Adnan & Kang Li, 2023. "Progress in Solid Oxide Fuel Cells with Hydrocarbon Fuels," Energies, MDPI, vol. 16(17), pages 1-36, September.
    9. Fan, Liyuan & Li, Chao'en & van Biert, Lindert & Zhou, Shou-Han & Tabish, Asif Nadeem & Mokhov, Anatoli & Aravind, Purushothaman Vellayani & Cai, Weiwei, 2022. "Advances on methane reforming in solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    10. Xu, Han & Dang, Zheng, 2016. "Lattice Boltzmann modeling of carbon deposition in porous anode of a solid oxide fuel cell with internal reforming," Applied Energy, Elsevier, vol. 178(C), pages 294-307.
    11. Park, Kwangjin & Lee, Sangho & Bae, Gyujong & Bae, Joongmyeon, 2015. "Performance analysis of Cu, Sn and Rh impregnated NiO/CGO91 anode for butane internal reforming SOFC at intermediate temperature," Renewable Energy, Elsevier, vol. 83(C), pages 483-490.
    12. Cai, Weizi & Zhou, Qian & Xie, Yongmin & Liu, Jiang & Long, Guohui & Cheng, Shuang & Liu, Meilin, 2016. "A direct carbon solid oxide fuel cell operated on a plant derived biofuel with natural catalyst," Applied Energy, Elsevier, vol. 179(C), pages 1232-1241.
    13. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.
    14. Qu, Jifa & Wang, Wei & Chen, Yubo & Deng, Xiang & Shao, Zongping, 2016. "Stable direct-methane solid oxide fuel cells with calcium-oxide-modified nickel-based anodes operating at reduced temperatures," Applied Energy, Elsevier, vol. 164(C), pages 563-571.
    15. Azizi, Mohammad Ali & Brouwer, Jacob, 2018. "Progress in solid oxide fuel cell-gas turbine hybrid power systems: System design and analysis, transient operation, controls and optimization," Applied Energy, Elsevier, vol. 215(C), pages 237-289.
    16. Saadabadi, S. Ali & Thallam Thattai, Aditya & Fan, Liyuan & Lindeboom, Ralph E.F. & Spanjers, Henri & Aravind, P.V., 2019. "Solid Oxide Fuel Cells fuelled with biogas: Potential and constraints," Renewable Energy, Elsevier, vol. 134(C), pages 194-214.
    17. Ahn, Ji Ho & Kim, Tong Seop, 2020. "Effect of oxygen supply method on the performance of a micro gas turbine-based triple combined cycle with oxy-combustion carbon capture," Energy, Elsevier, vol. 211(C).
    18. Milanese, Marco & Colangelo, Gianpiero & Laforgia, Domenico & de Risi, Arturo, 2017. "Multi-parameter optimization of double-loop fluidized bed solar reactor for thermochemical fuel production," Energy, Elsevier, vol. 134(C), pages 919-932.
    19. Ahn, Ji Ho & Seo, Min Hyung & Kim, Tong Seop, 2021. "Efficiency maximization of a quadruple power generation system with zero carbon emission," Energy, Elsevier, vol. 226(C).
    20. Prabu, V. & Jayanti, S., 2012. "Underground coal-air gasification based solid oxide fuel cell system," Applied Energy, Elsevier, vol. 94(C), pages 406-414.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:134:y:2014:i:c:p:342-348. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.