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Long term thermal stability of organic PCMs

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  • Behzadi, S.
  • Farid, M.M.

Abstract

Thermal energy storage using phase change materials (PCMs) have been a focal point in the efficient energy utilisation in buildings for over 30years. The possible use of PCM in buildings is becoming more and more attractive due to the large energy storage density and nearly isothermal nature of the PCM storage when compared to sensible heat storage. Although there is large amount of information available on this topic, literatures show very little information about the long term thermal performance of phase change materials. In this research, changes in thermal characteristics of two commercial organic PCMs when exposed to a constant temperature above their melting point were examined. The thermal characteristic (i.e. melting range and latent heat of fusion) of Rubitherm 21 (RT21, a paraffin mixture) and propyl stearic and palmitate mixture with a melting point in the range of 18–25°C were tested after an exposure to storage temperatures of 30 and 55°C. The results obtained indicated that the paraffin based mixture such as RT21 experienced a significant irreversible physical change with time. The data collected and analysis indicated a shift in the peak melting point from 21 to 28°C and increase in latent heat of fusion from 134 to 170J/g over a period of 120days when kept at a temperature of 55°C. On the other hand, the mixed esters experienced almost no change in mass due to their lower vapour pressure.

Suggested Citation

  • Behzadi, S. & Farid, M.M., 2014. "Long term thermal stability of organic PCMs," Applied Energy, Elsevier, vol. 122(C), pages 11-16.
    • Handle: RePEc:eee:appene:v:122:y:2014:i:c:p:11-16
    DOI: 10.1016/j.apenergy.2014.01.032
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    1. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    2. Giro-Paloma, Jessica & Oncins, Gerard & Barreneche, Camila & Martínez, Mònica & Fernández, A. Inés & Cabeza, Luisa F., 2013. "Physico-chemical and mechanical properties of microencapsulated phase change material," Applied Energy, Elsevier, vol. 109(C), pages 441-448.
    3. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    4. Sittisart, Pongphat & Farid, Mohammed M., 2011. "Fire retardants for phase change materials," Applied Energy, Elsevier, vol. 88(9), pages 3140-3145.
    5. He, Bo & Martin, Viktoria & Setterwall, Fredrik, 2004. "Phase transition temperature ranges and storage density of paraffin wax phase change materials," Energy, Elsevier, vol. 29(11), pages 1785-1804.
    6. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
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    3. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
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    6. Ikutegbe, Charles A. & Farid, Mohammed M., 2020. "Application of phase change material foam composites in the built environment: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    7. Ling, Haoshu & Chen, Chao & Wei, Shen & Guan, Yong & Ma, Caiwen & Xie, Guangya & Li, Na & Chen, Ziguang, 2015. "Effect of phase change materials on indoor thermal environment under different weather conditions and over a long time," Applied Energy, Elsevier, vol. 140(C), pages 329-337.
    8. Evdoxia Paroutoglou & Peter Fojan & Leonid Gurevich & Göran Hultmark & Alireza Afshari, 2021. "Thermal Analysis of Organic and Nanoencapsulated Electrospun Phase Change Materials," Energies, MDPI, vol. 14(4), pages 1-15, February.
    9. O’Connor, William E. & Warzoha, Ronald & Weigand, Rebecca & Fleischer, Amy S. & Wemhoff, Aaron P., 2014. "Thermal property prediction and measurement of organic phase change materials in the liquid phase near the melting point," Applied Energy, Elsevier, vol. 132(C), pages 496-506.
    10. Khan, Mohammed Mumtaz A. & Saidur, R. & Al-Sulaiman, Fahad A., 2017. "A review for phase change materials (PCMs) in solar absorption refrigeration systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 105-137.

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