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Alcohols as alkylating agents in heteroarene C–H functionalization

Author

Listed:
  • Jian Jin

    (Merck Center for Catalysis at Princeton University)

  • David W. C. MacMillan

    (Merck Center for Catalysis at Princeton University)

Abstract

The biochemical process of spin-centre shift is used to accomplish mild, non-traditional alkylation reactions using alcohols as radical precursors; this represents the first broadly applicable use of unactivated alcohols as latent alkylating reagents, achieved via the successful merger of photoredox and hydrogen atom transfer catalysis.

Suggested Citation

  • Jian Jin & David W. C. MacMillan, 2015. "Alcohols as alkylating agents in heteroarene C–H functionalization," Nature, Nature, vol. 525(7567), pages 87-90, September.
    • Handle: RePEc:nat:nature:v:525:y:2015:i:7567:d:10.1038_nature14885
    DOI: 10.1038/nature14885
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    Cited by:

    1. Hao Yang & Jinhui Xu & Hui Cao & Jie Wu & Dan Zhao, 2023. "Recovery of homogeneous photocatalysts by covalent organic framework membranes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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