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High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes

Author

Listed:
  • Laidong Zhou

    (University of Waterloo
    Argonne National Laboratory)

  • Tong-Tong Zuo

    (Justus Liebig University)

  • Chun Yuen Kwok

    (University of Waterloo)

  • Se Young Kim

    (University of Waterloo)

  • Abdeljalil Assoud

    (University of Waterloo)

  • Qiang Zhang

    (Oak Ridge National Laboratory)

  • Jürgen Janek

    (Justus Liebig University)

  • Linda F. Nazar

    (University of Waterloo
    Argonne National Laboratory)

Abstract

All-solid-state Li batteries (ASSBs) employing inorganic solid electrolytes offer improved safety and are exciting candidates for next-generation energy storage. Herein, we report a family of lithium mixed-metal chlorospinels, Li2InxSc0.666−xCl4 (0 ≤ x ≤ 0.666), with high ionic conductivity (up to 2.0 mS cm−1) owing to a highly disordered Li-ion distribution, and low electronic conductivity (4.7 × 10−10 S cm−1), which are implemented for high-performance ASSBs. Owing to the excellent interfacial stability of the SE against uncoated high-voltage cathode materials, ASSBs utilizing LiCoO2 or LiNi0.85Co0.1Mn0.05O2 exhibit superior rate capability and long-term cycling (up to 4.8 V versus Li+/Li) compared to state-of-the-art ASSBs. In particular, the ASSB with LiNi0.85Co0.1Mn0.05O2 exhibits a long life of >3,000 cycles with 80% capacity retention at room temperature. High cathode loadings are also demonstrated in ASSBs with stable capacity retention of >4 mAh cm−2 (~190 mAh g−1).

Suggested Citation

  • Laidong Zhou & Tong-Tong Zuo & Chun Yuen Kwok & Se Young Kim & Abdeljalil Assoud & Qiang Zhang & Jürgen Janek & Linda F. Nazar, 2022. "High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes," Nature Energy, Nature, vol. 7(1), pages 83-93, January.
    • Handle: RePEc:nat:natene:v:7:y:2022:i:1:d:10.1038_s41560-021-00952-0
    DOI: 10.1038/s41560-021-00952-0
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    Citations

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    Cited by:

    1. Xiaona Li & Jung Tae Kim & Jing Luo & Changtai Zhao & Yang Xu & Tao Mei & Ruying Li & Jianwen Liang & Xueliang Sun, 2024. "Structural regulation of halide superionic conductors for all-solid-state lithium batteries," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. Shumin Zhang & Feipeng Zhao & Jiatang Chen & Jiamin Fu & Jing Luo & Sandamini H. Alahakoon & Lo-Yueh Chang & Renfei Feng & Mohsen Shakouri & Jianwen Liang & Yang Zhao & Xiaona Li & Le He & Yining Huan, 2023. "A family of oxychloride amorphous solid electrolytes for long-cycling all-solid-state lithium batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Pushun Lu & Yu Xia & Guochen Sun & Dengxu Wu & Siyuan Wu & Wenlin Yan & Xiang Zhu & Jiaze Lu & Quanhai Niu & Shaochen Shi & Zhengju Sha & Liquan Chen & Hong Li & Fan Wu, 2023. "Realizing long-cycling all-solid-state Li-In||TiS2 batteries using Li6+xMxAs1-xS5I (M=Si, Sn) sulfide solid electrolytes," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    4. Guanjun Ji & Junxiong Wang & Zheng Liang & Kai Jia & Jun Ma & Zhaofeng Zhuang & Guangmin Zhou & Hui-Ming Cheng, 2023. "Direct regeneration of degraded lithium-ion battery cathodes with a multifunctional organic lithium salt," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Qidi Wang & Yunan Zhou & Xuelong Wang & Hao Guo & Shuiping Gong & Zhenpeng Yao & Fangting Wu & Jianlin Wang & Swapna Ganapathy & Xuedong Bai & Baohua Li & Chenglong Zhao & Jürgen Janek & Marnix Wagema, 2024. "Designing lithium halide solid electrolytes," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    6. Zhenyou Song & Tengrui Wang & Hua Yang & Wang Hay Kan & Yuwei Chen & Qian Yu & Likuo Wang & Yini Zhang & Yiming Dai & Huaican Chen & Wen Yin & Takashi Honda & Maxim Avdeev & Henghui Xu & Jiwei Ma & Yu, 2024. "Promoting high-voltage stability through local lattice distortion of halide solid electrolytes," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    7. Hiram Kwak & Jae-Seung Kim & Daseul Han & Jong Seok Kim & Juhyoun Park & Gihan Kwon & Seong-Min Bak & Unseon Heo & Changhyun Park & Hyun-Wook Lee & Kyung-Wan Nam & Dong-Hwa Seo & Yoon Seok Jung, 2023. "Boosting the interfacial superionic conduction of halide solid electrolytes for all-solid-state batteries," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    8. Lv Hu & Jinzhu Wang & Kai Wang & Zhenqi Gu & Zhiwei Xi & Hui Li & Fang Chen & Youxi Wang & Zhenyu Li & Cheng Ma, 2023. "A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

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