IDEAS home Printed from https://ideas.repec.org/a/nat/natene/v2y2017i3d10.1038_nenergy.2016.214.html
   My bibliography  Save this article

Self-assembled dynamic perovskite composite cathodes for intermediate temperature solid oxide fuel cells

Author

Listed:
  • J. Felix Shin

    (University of Liverpool)

  • Wen Xu

    (University of Liverpool)

  • Marco Zanella

    (University of Liverpool)

  • Karl Dawson

    (School of Engineering, University of Liverpool)

  • Stanislav N. Savvin

    (University of Liverpool)

  • John B. Claridge

    (University of Liverpool)

  • Matthew J. Rosseinsky

    (University of Liverpool)

Abstract

Electrode materials for intermediate temperature (500–700 ∘C) solid oxide fuel cells require electrical and mechanical stability to maintain performance during the cell lifetime. This has proven difficult to achieve for many candidate cathode materials and their derivatives with good transport and electrocatalytic properties because of reactivity towards cell components, and the fuels and oxidants. Here we present Ba0.5Sr0.5(Co0.7Fe0.3)0.6875W0.3125O3−δ (BSCFW), a self-assembled composite prepared through simple solid state synthesis, consisting of B-site cation ordered double perovskite and disordered single perovskite oxide phases, as a candidate cathode material. These phases interact by dynamic compositional change at the operating temperature, promoting both chemical stability through the increased amount of W in the catalytically active single perovskite provided from the W-reservoir double perovskite, and microstructural stability through reduced sintering of the supported catalytically active phase. This interactive catalyst-support system enabled stable high electrochemical activity through the synergic integration of the distinct properties of the two phases.

Suggested Citation

  • J. Felix Shin & Wen Xu & Marco Zanella & Karl Dawson & Stanislav N. Savvin & John B. Claridge & Matthew J. Rosseinsky, 2017. "Self-assembled dynamic perovskite composite cathodes for intermediate temperature solid oxide fuel cells," Nature Energy, Nature, vol. 2(3), pages 1-7, March.
    • Handle: RePEc:nat:natene:v:2:y:2017:i:3:d:10.1038_nenergy.2016.214
    DOI: 10.1038/nenergy.2016.214
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/nenergy2016214
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/nenergy.2016.214?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xuemei Li & Wengang Huang & Andraž Krajnc & Yuwei Yang & Atul Shukla & Jaeho Lee & Mehri Ghasemi & Isaac Martens & Bun Chan & Dominique Appadoo & Peng Chen & Xiaoming Wen & Julian A. Steele & Haira G., 2023. "Interfacial alloying between lead halide perovskite crystals and hybrid glasses," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Fang, Xiurong & Lin, Zijing, 2018. "Numerical study on the mechanical stress and mechanical failure of planar solid oxide fuel cell," Applied Energy, Elsevier, vol. 229(C), pages 63-68.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natene:v:2:y:2017:i:3:d:10.1038_nenergy.2016.214. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.