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Advances in understanding mechanisms underpinning lithium–air batteries

Author

Listed:
  • Doron Aurbach

    (Bar Ilan University)

  • Bryan D. McCloskey

    (University of California
    Lawrence Berkeley National Laboratory)

  • Linda F. Nazar

    (The Waterloo Institute for Nanotechnology, University of Waterloo)

  • Peter G. Bruce

    (Parks Road, University of Oxford)

Abstract

The rechargeable lithium–air battery has the highest theoretical specific energy of any rechargeable battery and could transform energy storage if a practical device could be realized. At the fundamental level, little was known about the reactions and processes that take place in the battery, representing a significant barrier to progress. Here, we review recent advances in understanding the chemistry and electrochemistry that govern the operation of the lithium–air battery, especially the reactions at the cathode. The mechanisms of O2 reduction to Li2O2 on discharge and the reverse process on charge are discussed in detail, as are their consequences for the rate and capacity of the battery. The various parasitic reactions involving the cathode and electrolyte during discharge and charge are also considered. We also provide views on understanding the stability of the cathode and electrolyte and examine design principles for better lithium–air batteries.

Suggested Citation

  • Doron Aurbach & Bryan D. McCloskey & Linda F. Nazar & Peter G. Bruce, 2016. "Advances in understanding mechanisms underpinning lithium–air batteries," Nature Energy, Nature, vol. 1(9), pages 1-11, September.
    • Handle: RePEc:nat:natene:v:1:y:2016:i:9:d:10.1038_nenergy.2016.128
    DOI: 10.1038/nenergy.2016.128
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    Cited by:

    1. Wang, Yuanhui & Hao, Liang & Bai, Minli, 2023. "Modeling the influence of water on the performance of non-aqueous Li-O2 batteries," Applied Energy, Elsevier, vol. 330(PB).
    2. Deqing Cao & Chuan Tan & Yuhui Chen, 2022. "Oxidative decomposition mechanisms of lithium carbonate on carbon substrates in lithium battery chemistries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Wang, Yuanhui & Hao, Liang & Bai, Minli, 2022. "Modeling the multi-step discharge and charge reaction mechanisms of non-aqueous Li-O2 batteries," Applied Energy, Elsevier, vol. 317(C).
    4. Anatoly Antipov & Roman Pichugov & Lilia Abunaeva & Shengfu Tong & Mikhail Petrov & Alla Pustovalova & Ivan Speshilov & Natalia Kartashova & Pavel Loktionov & Alexander Modestov & Artem Glazkov, 2022. "Halogen Hybrid Flow Batteries Advances for Stationary Chemical Power Sources Technologies," Energies, MDPI, vol. 15(19), pages 1-20, October.
    5. Pitchai Ragupathy & Santoshkumar Dattatray Bhat & Nallathamby Kalaiselvi, 2023. "Electrochemical energy storage and conversion: An overview," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 12(2), March.

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