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Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework

Author

Listed:
  • Linfeng Liang

    (Chinese Academy of Sciences, Fuzhou
    University of Science and Technology of China)

  • Caiping Liu

    (Chinese Academy of Sciences, Fuzhou)

  • Feilong Jiang

    (Chinese Academy of Sciences, Fuzhou)

  • Qihui Chen

    (Chinese Academy of Sciences, Fuzhou)

  • Linjie Zhang

    (Chinese Academy of Sciences, Fuzhou)

  • Hui Xue

    (Chinese Academy of Sciences, Fuzhou)

  • Hai-Long Jiang

    (University of Science and Technology of China
    Hefei National Laboratory for Physical Sciences at the Microscale)

  • Jinjie Qian

    (Wenzhou University)

  • Daqiang Yuan

    (Chinese Academy of Sciences, Fuzhou)

  • Maochun Hong

    (Chinese Academy of Sciences, Fuzhou
    University of Science and Technology of China)

Abstract

Considering the rapid increase of CO2 emission, especially from power plants, there is a constant need for materials which can effectively eliminate post-combustion CO2 (the main component: CO2/N2 = 15/85). Here, we show the design and synthesis of a Cu(II) metal-organic framework (FJI-H14) with a high density of active sites, which displays unusual acid and base stability and high volumetric uptake (171 cm3 cm−3) of CO2 under ambient conditions (298 K, 1 atm), making it a potential adsorbing agent for post-combustion CO2. Moreover, CO2 from simulated post-combustion flue gas can be smoothly converted into corresponding cyclic carbonates by the FJI-H14 catalyst. Such high CO2 adsorption capacity and moderate catalytic activity may result from the synergistic effect of multiple active sites.

Suggested Citation

  • Linfeng Liang & Caiping Liu & Feilong Jiang & Qihui Chen & Linjie Zhang & Hui Xue & Hai-Long Jiang & Jinjie Qian & Daqiang Yuan & Maochun Hong, 2017. "Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework," Nature Communications, Nature, vol. 8(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_s41467-017-01166-3
    DOI: 10.1038/s41467-017-01166-3
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    Cited by:

    1. Yoro, Kelvin O. & Daramola, Michael O. & Sekoai, Patrick T. & Armah, Edward K. & Wilson, Uwemedimo N., 2021. "Advances and emerging techniques for energy recovery during absorptive CO2 capture: A review of process and non-process integration-based strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).

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