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Synthesis of ketones from biomass-derived feedstock

Author

Listed:
  • Qinglei Meng

    (Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences)

  • Minqiang Hou

    (Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences)

  • Huizhen Liu

    (Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences
    School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences)

  • Jinliang Song

    (Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences)

  • Buxing Han

    (Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences
    School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences)

Abstract

Cyclohexanone and its derivatives are very important chemicals, which are currently produced mainly by oxidation of cyclohexane or alkylcyclohexane, hydrogenation of phenols, and alkylation of cyclohexanone. Here we report that bromide salt-modified Pd/C in H2O/CH2Cl2 can efficiently catalyse the transformation of aromatic ethers, which can be derived from biomass, to cyclohexanone and its derivatives via hydrogenation and hydrolysis processes. The yield of cyclohexanone from anisole can reach 96%, and the yields of cyclohexanone derivatives produced from the aromatic ethers, which can be extracted from plants or derived from lignin, are also satisfactory. Detailed study shows that the Pd, bromide salt and H2O/CH2Cl2 work cooperatively to promote the desired reaction and inhibit the side reaction. Thus high yields of desired products can be obtained. This work opens the way for production of ketones from aromatic ethers that can be derived from biomass.

Suggested Citation

  • Qinglei Meng & Minqiang Hou & Huizhen Liu & Jinliang Song & Buxing Han, 2017. "Synthesis of ketones from biomass-derived feedstock," Nature Communications, Nature, vol. 8(1), pages 1-8, April.
    • Handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_ncomms14190
    DOI: 10.1038/ncomms14190
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    Cited by:

    1. Kim, Seong-Ju & Kim, Ga-Hee & Um, Byung-Hwan, 2022. "Use of an alkaline catalyst with ethanol-water as a co-solvent in the hydrothermal liquefaction of the Korean native kenaf: An analysis of the light oil and heavy oil characteristics," Energy, Elsevier, vol. 249(C).
    2. Tao Peng & Wenbin Zhang & Baiyao Liang & Guanwu Lian & Yun Zhang & Wei Zhao, 2023. "Electrocatalytic valorization of lignocellulose-derived aromatics at industrial-scale current densities," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    3. Jiang, Peng & Wang, Chenhan & She, Wenjie & Ye, Wenkai & Li, Yinchen & Ji, Tuo & Mu, Liwen & Lu, Xiaohua & Zhu, Jiahua, 2026. "Machine learning accelerated data generation, process modelling and system optimization for biomass conversion and valorization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 226(PD).

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