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A bi-functional device for self-powered electrochromic window and self-rechargeable transparent battery applications

Author

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  • Jinmin Wang

    (Luminous! Centre of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798, Singapore
    School of Urban Development and Environmental Engineering, Shanghai Second Polytechnic University)

  • Lei Zhang

    (School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore)

  • Le Yu

    (School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore)

  • Zhihui Jiao

    (Luminous! Centre of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798, Singapore)

  • Huaqing Xie

    (School of Urban Development and Environmental Engineering, Shanghai Second Polytechnic University)

  • Xiong Wen (David) Lou

    (School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore)

  • Xiao Wei Sun

    (Luminous! Centre of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798, Singapore)

Abstract

Electrochromic smart windows are regarded as a good choice for green buildings. However, conventional devices need external biases to operate, which causes additional energy consumption. Here we report a self-powered electrochromic window, which can be used as a self-rechargeable battery. We use aluminium to reduce Prussian blue (PB, blue in colour) to Prussian white (PW, colourless) in potassium chloride electrolyte, realizing a device capable of self-bleaching. Interestingly, the device can be self-recovered (gaining blue appearance again) by simply disconnecting the aluminium and PB electrodes, which is due to the spontaneous oxidation of PW to PB by the dissolved oxygen in aqueous solution. The self-operated bleaching and colouration suggest another important function of the device: a self-rechargeable transparent battery. Thus the PB/aluminium device we report here is bifunctional, that is, it is a self-powered electrochromic window as well as a self-rechargeable transparent battery.

Suggested Citation

  • Jinmin Wang & Lei Zhang & Le Yu & Zhihui Jiao & Huaqing Xie & Xiong Wen (David) Lou & Xiao Wei Sun, 2014. "A bi-functional device for self-powered electrochromic window and self-rechargeable transparent battery applications," Nature Communications, Nature, vol. 5(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms5921
    DOI: 10.1038/ncomms5921
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    Cited by:

    1. Mikhail Vasiliev & Mohammad Nur-E-Alam & Kamal Alameh, 2019. "Recent Developments in Solar Energy-Harvesting Technologies for Building Integration and Distributed Energy Generation," Energies, MDPI, vol. 12(6), pages 1-23, March.

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