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Autonomous self-healing organic crystals for nonlinear optics

Author

Listed:
  • Saikat Mondal

    (Indian Institute of Science Education and Research Kolkata)

  • Pratap Tanari

    (Indian Institute of Science Education and Research Kolkata)

  • Samrat Roy

    (Indian Institute of Science Education and Research Kolkata)

  • Surojit Bhunia

    (Indian Institute of Science Education and Research Kolkata)

  • Rituparno Chowdhury

    (Indian Institute of Science Education and Research Kolkata)

  • Arun K. Pal

    (Indian Association for the Cultivation of Science)

  • Ayan Datta

    (Indian Association for the Cultivation of Science)

  • Bipul Pal

    (Indian Institute of Science Education and Research Kolkata)

  • C. Malla Reddy

    (Indian Institute of Science Education and Research Kolkata)

Abstract

Non-centrosymmetric molecular crystals have a plethora of applications, such as piezoelectric transducers, energy storage and nonlinear optical materials owing to their unique structural order which is absent in other synthetic materials. As most crystals are brittle, their efficiency declines upon prolonged usage due to fatigue or catastrophic failure, limiting their utilities. Some natural substances, like bone, enamel, leaf and skin, function efficiently, last a life-time, thanks to their inherent self-healing nature. Therefore, incorporating self-healing ability in crystalline materials will greatly broaden their scope. Here, we report single crystals of a dibenzoate derivative, capable of self-healing within milliseconds via autonomous actuation. Systematic quantitative experiments reveal the limit of mechanical forces that the self-healing crystals can withstand. As a proof-of-concept, we also demonstrate that our self-healed crystals can retain their second harmonic generation (SHG) with high efficiency. Kinematic analysis of the actuation in our system also revealed its impressive performance parameters, and shows actuation response times in the millisecond range.

Suggested Citation

  • Saikat Mondal & Pratap Tanari & Samrat Roy & Surojit Bhunia & Rituparno Chowdhury & Arun K. Pal & Ayan Datta & Bipul Pal & C. Malla Reddy, 2023. "Autonomous self-healing organic crystals for nonlinear optics," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42131-7
    DOI: 10.1038/s41467-023-42131-7
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    References listed on IDEAS

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    1. Takuya Taniguchi & Haruki Sugiyama & Hidehiro Uekusa & Motoo Shiro & Toru Asahi & Hideko Koshima, 2018. "Walking and rolling of crystals induced thermally by phase transition," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. Mark Burnworth & Liming Tang & Justin R. Kumpfer & Andrew J. Duncan & Frederick L. Beyer & Gina L. Fiore & Stuart J. Rowan & Christoph Weder, 2011. "Optically healable supramolecular polymers," Nature, Nature, vol. 472(7343), pages 334-337, April.
    3. S. R. White & N. R. Sottos & P. H. Geubelle & J. S. Moore & M. R. Kessler & S. R. Sriram & E. N. Brown & S. Viswanathan, 2001. "Autonomic healing of polymer composites," Nature, Nature, vol. 409(6822), pages 794-797, February.
    4. Christopher M. Barr & Ta Duong & Daniel C. Bufford & Zachary Milne & Abhilash Molkeri & Nathan M. Heckman & David P. Adams & Ankit Srivastava & Khalid Hattar & Michael J. Demkowicz & Brad L. Boyce, 2023. "Autonomous healing of fatigue cracks via cold welding," Nature, Nature, vol. 620(7974), pages 552-556, August.
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