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Strain-regulated Gibbs free energy enables reversible redox chemistry of chalcogenides for sodium ion batteries

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  • Minxia Jiang

    (Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology)

  • Yingjie Hu

    (Nanjing Xiaozhuang University)

  • Baoguang Mao

    (Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology)

  • Yixin Wang

    (Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology)

  • Zhen Yang

    (Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology)

  • Tao Meng

    (Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology)

  • Xin Wang

    (Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology)

  • Minhua Cao

    (Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology)

Abstract

Manipulating the reversible redox chemistry of transition metal dichalcogenides for energy storage often faces great challenges as it is difficult to regulate the discharged products directly. Herein we report that tensile-strained MoSe2 (TS-MoSe2) can act as a host to transfer its strain to corresponding discharged product Mo, thus contributing to the regulation of Gibbs free energy change (ΔG) and enabling a reversible sodium storage mechanism. The inherited strain results in lattice distortion of Mo, which adjusts the d-band center upshifted closer to the Fermi level to enhance the adsorbability of Na2Se, thereby leading to a decreased ΔG of the redox chemistry between Mo/Na2Se and MoSe2. Ex situ and in situ experiments revealed that, unlike the unstrained MoSe2, TS-MoSe2 shows a highly reversible sodium storage, along with an evidently improved reaction kinetics. This work sheds light on the study on electrochemical energy storage mechanism of other electrode materials.

Suggested Citation

  • Minxia Jiang & Yingjie Hu & Baoguang Mao & Yixin Wang & Zhen Yang & Tao Meng & Xin Wang & Minhua Cao, 2022. "Strain-regulated Gibbs free energy enables reversible redox chemistry of chalcogenides for sodium ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33329-2
    DOI: 10.1038/s41467-022-33329-2
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    References listed on IDEAS

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