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Liquid crystalline 2D borophene oxide for inorganic optical devices

Author

Listed:
  • Tetsuya Kambe

    (Tokyo Institute of Technology
    JST-ERATO, Tokyo Institute of Technology)

  • Shotaro Imaoka

    (Tokyo Institute of Technology)

  • Misa Shimizu

    (Tokyo Institute of Technology)

  • Reina Hosono

    (Tokyo Institute of Technology)

  • Dongwan Yan

    (Tokyo Institute of Technology)

  • Hinayo Taya

    (Tokyo Institute of Technology)

  • Masahiro Katakura

    (Tokyo Institute of Technology)

  • Hirona Nakamura

    (Tokyo Institute of Technology)

  • Shoichi Kubo

    (Tokyo Institute of Technology)

  • Atsushi Shishido

    (Tokyo Institute of Technology)

  • Kimihisa Yamamoto

    (Tokyo Institute of Technology
    JST-ERATO, Tokyo Institute of Technology)

Abstract

Borophene has been recently proposed as a next-generation two-dimensional material with promising electronic and optical properties. However, its instability has thus far limited its large-scale applications. Here, we investigate a liquid-state borophene analogue with an ordered layer structure derived from two-dimensional borophene oxide. The material structure, phase transition features and basic properties are revealed by using X-ray analysis, optical and electron microscopy, and thermal characterization. The obtained liquid crystal exhibits high thermal stability at temperatures up to 350 °C and an optical switching behaviour driven by a low voltage of 1 V.

Suggested Citation

  • Tetsuya Kambe & Shotaro Imaoka & Misa Shimizu & Reina Hosono & Dongwan Yan & Hinayo Taya & Masahiro Katakura & Hirona Nakamura & Shoichi Kubo & Atsushi Shishido & Kimihisa Yamamoto, 2022. "Liquid crystalline 2D borophene oxide for inorganic optical devices," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28625-w
    DOI: 10.1038/s41467-022-28625-w
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    References listed on IDEAS

    as
    1. Zachary A. Piazza & Han-Shi Hu & Wei-Li Li & Ya-Fan Zhao & Jun Li & Lai-Sheng Wang, 2014. "Planar hexagonal B36 as a potential basis for extended single-atom layer boron sheets," Nature Communications, Nature, vol. 5(1), pages 1-6, May.
    2. Jianing Chen & Michela Badioli & Pablo Alonso-González & Sukosin Thongrattanasiri & Florian Huth & Johann Osmond & Marko Spasenović & Alba Centeno & Amaia Pesquera & Philippe Godignon & Amaia Zurutuza, 2012. "Optical nano-imaging of gate-tunable graphene plasmons," Nature, Nature, vol. 487(7405), pages 77-81, July.
    3. Felix M. van der Kooij & Katerina Kassapidou & Henk N. W. Lekkerkerker, 2000. "Liquid crystal phase transitions in suspensions of polydisperse plate-like particles," Nature, Nature, vol. 406(6798), pages 868-871, August.
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    1. Changjae Lee & Soon Mo Park & Soobin Kim & Yun-Seok Choi & Geonhyeong Park & Yun Chan Kang & Chong Min Koo & Seon Joon Kim & Dong Ki Yoon, 2022. "Field-induced orientational switching produces vertically aligned Ti3C2Tx MXene nanosheets," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

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