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Thermal Stability of NASICON-Type Na 3 V 2 (PO 4 ) 3 and Na 4 VMn(PO 4 ) 3 as Cathode Materials for Sodium-ion Batteries

Author

Listed:
  • Ruslan R. Samigullin

    (Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia)

  • Maxim V. Zakharkin

    (Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia)

  • Oleg A. Drozhzhin

    (Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia)

  • Evgeny V. Antipov

    (Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia
    Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, 143026 Moscow, Russia)

Abstract

The thermal stability of NASICON-type cathode materials for sodium-ion batteries was studied using differential scanning calorimetry (DSC) and in situ high-temperature powder X-ray diffraction (HTPXRD) applied to the electrodes in a pristine or charged state. Na 3 V 2 (PO 4 ) 3 and Na 4 VMn(PO 4 ) 3 were analyzed for their peak temperatures and the exothermic effect values of their decomposition processes, as well as the phase transformations that took place upon heating. The obtained results indicate that Mn-substituted cathode material demonstrates much poorer thermal stability in the charged state, although pristine samples of both materials exhibit similar thermal behavior without any DSC peaks or temperature-induced phase transitions in the studied temperature range. The in situ HTPXRD revealed the amorphization of desodiated Na 4 VMn(PO 4 ) 3 -based electrodes occurring at 150~250 °C.

Suggested Citation

  • Ruslan R. Samigullin & Maxim V. Zakharkin & Oleg A. Drozhzhin & Evgeny V. Antipov, 2023. "Thermal Stability of NASICON-Type Na 3 V 2 (PO 4 ) 3 and Na 4 VMn(PO 4 ) 3 as Cathode Materials for Sodium-ion Batteries," Energies, MDPI, vol. 16(7), pages 1-13, March.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:7:p:3051-:d:1108777
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    References listed on IDEAS

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    1. Guochun Yan & Sathiya Mariyappan & Gwenaelle Rousse & Quentin Jacquet & Michael Deschamps & Renald David & Boris Mirvaux & John William Freeland & Jean-Marie Tarascon, 2019. "Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    2. Yuqi Li & Quan Zhou & Suting Weng & Feixiang Ding & Xingguo Qi & Jiaze Lu & Yu Li & Xiao Zhang & Xiaohui Rong & Yaxiang Lu & Xuefeng Wang & Ruijuan Xiao & Hong Li & Xuejie Huang & Liquan Chen & Yong-S, 2022. "Interfacial engineering to achieve an energy density of over 200 Wh kg−1 in sodium batteries," Nature Energy, Nature, vol. 7(6), pages 511-519, June.
    3. Wen Zhu & Yuesheng Wang & Dongqiang Liu & Vincent Gariépy & Catherine Gagnon & Ashok Vijh & Michel L. Trudeau & Karim Zaghib, 2018. "Application of Operando X-ray Diffractometry in Various Aspects of the Investigations of Lithium/Sodium-Ion Batteries," Energies, MDPI, vol. 11(11), pages 1-41, November.
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