IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v247y2025ics0960148125007578.html

Cascade method for extracting high-value compounds from corn straw by combining hydrothermal pretreatment and catalytic pyrolysis

Author

Listed:
  • Nie, Siman
  • Lv, Peng
  • Cheng, Yuyan
  • Wang, Jiaofei
  • Bai, Yonghui
  • Song, Xudong
  • Su, Weiguang
  • Wei, Juntao
  • Yu, Guangsuo

Abstract

The production of high-value chemicals through the targeted pyrolysis of biomass can achieves the utilization of biomass waste as an energy source. This study presents a method for preparing high value-added bio-oil by integrating hydrothermal pretreatment (HTP) of corn straw (CS) with catalytic pyrolysis. The evolution of the physicochemical structure of pretreated samples under different conditions was detailed analyzed and the effects of HTP on the composition and distribution of pyrolysis products was investigated. Furthermore, different types of zeolite catalysts, including USY, Beta, and ZSM-5, were employed for the catalytic pyrolysis of HTP-treated samples. The results showed that HTP significantly enhanced the energy density of CS and modified its pyrolysis characteristics. The glucopyranose yield in HTP-treated samples substantially exceeded that of untreated CS. Owing to variations in the distribution of surface acidic sites and pore structures, different zeolite types exhibited distinct impacts on the composition and distribution of bio-oil components, particularly in enhancing the yield of aromatic compounds. Notably, the aromatic yield of CS160 showed a 1.6-fold increase compared to untreated CS when subjected to ZSM-5 catalytic pyrolysis. This study provides significant guidance for the preparation of high-value chemicals from biomass resources.

Suggested Citation

  • Nie, Siman & Lv, Peng & Cheng, Yuyan & Wang, Jiaofei & Bai, Yonghui & Song, Xudong & Su, Weiguang & Wei, Juntao & Yu, Guangsuo, 2025. "Cascade method for extracting high-value compounds from corn straw by combining hydrothermal pretreatment and catalytic pyrolysis," Renewable Energy, Elsevier, vol. 247(C).
    • Handle: RePEc:eee:renene:v:247:y:2025:i:c:s0960148125007578
    DOI: 10.1016/j.renene.2025.123095
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148125007578
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2025.123095?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Parascanu, M.M. & Sandoval-Salas, F. & Soreanu, G. & Valverde, J.L. & Sanchez-Silva, L., 2017. "Valorization of Mexican biomasses through pyrolysis, combustion and gasification processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 509-522.
    2. Srirangan, Kajan & Akawi, Lamees & Moo-Young, Murray & Chou, C. Perry, 2012. "Towards sustainable production of clean energy carriers from biomass resources," Applied Energy, Elsevier, vol. 100(C), pages 172-186.
    3. Ramanauske, Neringa & Balezentis, Tomas & Streimikiene, Dalia, 2023. "Biomass use and its implications for bioeconomy development: A resource efficiency perspective for the European countries," Technological Forecasting and Social Change, Elsevier, vol. 193(C).
    4. Liang, Jie & Shan, Guangcun & Sun, Yifei, 2021. "Catalytic fast pyrolysis of lignocellulosic biomass: Critical role of zeolite catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    5. Su, Chi Wei & Shao, Xuefeng & Jia, Zhijie & Nepal, Rabindra & Umar, Muhammad & Qin, Meng, 2023. "The rise of green energy metal: Could lithium threaten the status of oil?," Energy Economics, Elsevier, vol. 121(C).
    6. Bingqing Zhang & Nathan J. Chellman & Jed O. Kaplan & Loretta J. Mickley & Takamitsu Ito & Xuan Wang & Sophia M. Wensman & Drake McCrimmon & Jørgen Peder Steffensen & Joseph R. McConnell & Pengfei Liu, 2024. "Improved biomass burning emissions from 1750 to 2010 using ice core records and inverse modeling," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Onumaegbu, C. & Mooney, J. & Alaswad, A. & Olabi, A.G., 2018. "Pre-treatment methods for production of biofuel from microalgae biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 93(C), pages 16-26.
    8. Wang, Qi & Xu, XiaoFeng & Wu, JiaLong & Han, Yu & Zheng, WenChang & Wang, Shuang, 2024. "Catalytic hydrothermal reaction of biomass and its application in blast furnace injection: Physicochemical, conversion mechanism, combustion behavior," Renewable Energy, Elsevier, vol. 237(PB).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xu, Hao & Hungwe, Douglas & Yang, Pu & Yu, Mengzhu & Tie, Hieng Ong & Yoshikawa, Kunio & Takahashi, Fumitake, 2026. "Integrated hydrothermal carbonization and pyrolysis for valorizing high-moisture biomass: Structural evolution and energy efficiency evaluation," Renewable Energy, Elsevier, vol. 258(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Xiao-Qing & Wu, Tong & Zhong, Huaming & Su, Chi-Wei, 2023. "Bubble behaviors in nickel price: What roles do geopolitical risk and speculation play?," Resources Policy, Elsevier, vol. 83(C).
    2. Wang, Fanyi & Ma, Wanying & Mirza, Nawazish & Altuntaş, Mehmet, 2023. "Green financing, financial uncertainty, geopolitical risk, and oil prices volatility," Resources Policy, Elsevier, vol. 83(C).
    3. Sun, Yanpeng & Song, Yuru & Long, Chi & Qin, Meng & Lobonţ, Oana-Ramona, 2023. "How to improve global environmental governance? Lessons learned from climate risk and climate policy uncertainty," Economic Analysis and Policy, Elsevier, vol. 80(C), pages 1666-1676.
    4. Bauer, Fredric & Hulteberg, Christian, 2014. "Isobutanol from glycerine – A techno-economic evaluation of a new biofuel production process," Applied Energy, Elsevier, vol. 122(C), pages 261-268.
    5. Yang, Xiaoming & Islam, Md. Monirul & Mentel, Grzegorz & Ahmad, Ashfaq & Vasa, László, 2024. "Synergistic dynamics unveiled: Interplay between rare earth prices, clean energy innovations, and tech companies' market resilience amidst the Covid-19 pandemic and Russia-Ukraine conflict," Resources Policy, Elsevier, vol. 89(C).
    6. Zhao, Qian & Wang, Lu & Stan, Sebastian-Emanuel & Mirza, Nawazish, 2024. "Can artificial intelligence help accelerate the transition to renewable energy?," Energy Economics, Elsevier, vol. 134(C).
    7. Caspeta, Luis & Caro-Bermúdez, Mario A. & Ponce-Noyola, Teresa & Martinez, Alfredo, 2014. "Enzymatic hydrolysis at high-solids loadings for the conversion of agave bagasse to fuel ethanol," Applied Energy, Elsevier, vol. 113(C), pages 277-286.
    8. Toka, Agorasti & Iakovou, Eleftherios & Vlachos, Dimitrios & Tsolakis, Naoum & Grigoriadou, Anastasia-Loukia, 2014. "Managing the diffusion of biomass in the residential energy sector: An illustrative real-world case study," Applied Energy, Elsevier, vol. 129(C), pages 56-69.
    9. Manuel Au-Yong-Oliveira & Camila Marinho & Valentina Chkoniya & Elisabete S. Vieira & Sandra Filipe, 2025. "Sustainable Food Supply Chains in Maritime Ports: A Review Across Management, Economic, and Social Dimensions," Economia agro-alimentare, FrancoAngeli Editore, vol. 2025(2), pages 7-34.
    10. López-González, D. & Puig-Gamero, M. & Acién, F.G. & García-Cuadra, F. & Valverde, J.L. & Sanchez-Silva, L., 2015. "Energetic, economic and environmental assessment of the pyrolysis and combustion of microalgae and their oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1752-1770.
    11. Tiwari, Sunil, 2024. "Impact of Fintech on natural resources management: How financial impacts shape the association?," Resources Policy, Elsevier, vol. 90(C).
    12. Hu, Yulin & Gong, Mengyue & Feng, Shanghuan & Xu, Chunbao (Charles) & Bassi, Amarjeet, 2019. "A review of recent developments of pre-treatment technologies and hydrothermal liquefaction of microalgae for bio-crude oil production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 476-492.
    13. Yukun Cao & Jingxuan Cai & Xiangyue Liu, 2024. "RETRACTED ARTICLE: Advancing toward a sustainable future: assessing the impact of energy transition, circular economy, and international trade on carbon footprint," Economic Change and Restructuring, Springer, vol. 57(2), pages 1-26, April.
    14. Su, Chi-Wei & Wang, Dan & Mirza, Nawazish & Zhong, Yifan & Umar, Muhammad, 2023. "The impact of consumer confidence on oil prices," Energy Economics, Elsevier, vol. 124(C).
    15. Schipfer, Fabian & Kranzl, Lukas, 2019. "Techno-economic evaluation of biomass-to-end-use chains based on densified bioenergy carriers (dBECs)," Applied Energy, Elsevier, vol. 239(C), pages 715-724.
    16. Dagar, Vishal & Dagher, Leila & Rao, Amar & Doytch, Nadia & Kagzi, Muneza, 2024. "Economic policy uncertainty: Global energy security with diversification," Economic Analysis and Policy, Elsevier, vol. 82(C), pages 248-263.
    17. Seckin, Candeniz & Bayulken, Ahmet R., 2013. "Extended Exergy Accounting (EEA) analysis of municipal wastewater treatment – Determination of environmental remediation cost for municipal wastewater," Applied Energy, Elsevier, vol. 110(C), pages 55-64.
    18. Wilberforce, Tabbi & El Hassan, Zaki & Durrant, A. & Thompson, J. & Soudan, Bassel & Olabi, A.G., 2019. "Overview of ocean power technology," Energy, Elsevier, vol. 175(C), pages 165-181.
    19. Wądrzyk, Mariusz & Grzywacz, Przemysław & Plata, Marek & Soprych, Piotr & Janus, Rafał & Lewandowski, Marek & Korzeniowski, Łukasz, 2025. "Sustainable H2-rich bio-syngas production from high moisture wastes: Steam gasification of hydrochars obtained from apple pomace in single and binary solvent systems," Renewable Energy, Elsevier, vol. 245(C).
    20. Su, Chi Wei & Wei, Shenkai & Wang, Yan & Tao, Ran, 2024. "How does climate policy uncertainty affect the carbon market?," Technological Forecasting and Social Change, Elsevier, vol. 200(C).

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:247:y:2025:i:c:s0960148125007578. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.