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Facile fabrication of shape-stable phase change materials based green composite for passive conditioning in buildings

Author

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  • Sarkar, Chandrani
  • Bhattacharya, Abhishek
  • Ashagre, Tewodros Belay
  • Verma, Rahul
  • Rakshit, Dibakar
  • Saha, Sampa

Abstract

Biopolymer, PHBV [Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)] has been demonstrated to provide great support to enhance the shape stability of n-eicosane, phase change material (PCM). The green composite comprising of PHBV and m-PCM (modified PCM) has shown enormous potential to be considered for thermal energy storage in buildings. Post fabrication, the composite film was exposed to corona treatment for improving their adhesion with building materials. Results showed that both corona-treated and non-treated m-PCM/PHBV have high thermal energy storage capability (>98 %). For instance, corona-treated film with a phase transition enthalpy of 184.9 ± 12.8 J g−1 exhibited high phase transfer repeatability and thermal reliability. The isothermal and non-isothermal DSC study revealed the optimum heat charging and discharging of the treated film, i.e., 21 °C–45 °C. The present study also demonstrated the impact of the incorporation of m-PCM/PHBV film on the thermal behavior of building materials by passive design strategy. The experimental testing of bricks containing m-PCM/PHBV under actual conditions was carried out at Delhi, India for five days (Sep 30, 2023 to Oct 4, 2023). A substantial reduction of temperature (∼7.5 °C) was observed in the bottom part of the brick having m-PCM/PHBV films, signifying their potential to be considered for passive conditioning in buildings.

Suggested Citation

  • Sarkar, Chandrani & Bhattacharya, Abhishek & Ashagre, Tewodros Belay & Verma, Rahul & Rakshit, Dibakar & Saha, Sampa, 2025. "Facile fabrication of shape-stable phase change materials based green composite for passive conditioning in buildings," Renewable Energy, Elsevier, vol. 247(C).
    • Handle: RePEc:eee:renene:v:247:y:2025:i:c:s0960148125006081
    DOI: 10.1016/j.renene.2025.122946
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    References listed on IDEAS

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    1. Pandey, Kalpana & Ali, Sana Fatima & Gupta, Sumit Kumar & Saikia, Pranaynil & Rakshit, Dibakar & Saha, Sampa, 2021. "Facile technique to encapsulate phase change material in an amphiphilic polymeric matrix for thermal energy storage," Applied Energy, Elsevier, vol. 292(C).
    2. Wang, Lijiu & Meng, Duo, 2010. "Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 87(8), pages 2660-2665, August.
    3. Saxena, Rajat & Rakshit, Dibakar & Kaushik, S.C., 2020. "Experimental assessment of Phase Change Material (PCM) embedded bricks for passive conditioning in buildings," Renewable Energy, Elsevier, vol. 149(C), pages 587-599.
    4. Azad, Abdus Salam & Rakshit, Dibakar & Patil, K.N., 2018. "Model development and evaluation of global and diffuse luminous efficacy for humid sub-tropical region," Renewable Energy, Elsevier, vol. 119(C), pages 375-387.
    5. Panchabikesan, Karthik & Vellaisamy, Kumaresan & Ramalingam, Velraj, 2017. "Passive cooling potential in buildings under various climatic conditions in India," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 1236-1252.
    6. Sun, Jingmeng & Zhao, Junqi & Zhang, Weiye & Xu, Jianuo & Wang, Beibei & Wang, Xuanye & Zhou, Jun & Guo, Hongwu & Liu, Yi, 2023. "Composites with a Novel Core–shell Structural Expanded Perlite/Polyethylene glycol Composite PCM as Novel Green Energy Storage Composites for Building Energy Conservation," Applied Energy, Elsevier, vol. 330(PA).
    7. Faraj, Khaireldin & Khaled, Mahmoud & Faraj, Jalal & Hachem, Farouk & Castelain, Cathy, 2020. "Phase change material thermal energy storage systems for cooling applications in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    8. Sun, Kun & Liu, Huan & Wang, Xiaodong & Wu, Dezhen, 2019. "Innovative design of superhydrophobic thermal energy-storage materials by microencapsulation of n-docosane with nanostructured ZnO/SiO2 shell," Applied Energy, Elsevier, vol. 237(C), pages 549-565.
    9. Mu, Mulan & Basheer, P.A.M. & Sha, Wei & Bai, Yun & McNally, Tony, 2016. "Shape stabilised phase change materials based on a high melt viscosity HDPE and paraffin waxes," Applied Energy, Elsevier, vol. 162(C), pages 68-82.
    10. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
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