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Dielectric alignment of a non-polar molecule substituting a polar molecule in a lattice of molecular dipoles

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  • Biemond, J.

Abstract

The dielectric alignment of a dilute non-polar component in a polar solvent may be determined by NMR spectroscopy. In this paper a series expansion of the alignment up to second order terms in the dipolar interaction is presented for a non-polar molecule replacing a single polar molecule in a rigid lattice of molecular dipoles. Assuming isotropic polarizabilities for all molecules Van Vleck earlier applied the lattice model in a theory of the dielectric constant of a dilute solution.

Suggested Citation

  • Biemond, J., 1977. "Dielectric alignment of a non-polar molecule substituting a polar molecule in a lattice of molecular dipoles," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 88(2), pages 385-394.
  • Handle: RePEc:eee:phsmap:v:88:y:1977:i:2:p:385-394
    DOI: 10.1016/0378-4371(77)90012-7
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