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Influence of the stick-slip transition on the electrokinetic behavior of nanoporous material

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  • Cheikh, Christophe
  • Koper, Ger

Abstract

Electrokinetic phenomena exhibiting discontinuities are described in terms of a stick-slip transition. The flux-force equations are partially linear and in the linear regimes the coefficients satisfy Onsager's reciprocal relations. From an interpretation of existing data on ion exchange membranes we find a linear dependence of the slip length with the surface potential. We conclude that slippage offers an alternative explanation for the so-called anomalous surface conduction, as often found in electrokinetic phenomena. This would imply an enhancement of electrokinetic effects in nanopores.

Suggested Citation

  • Cheikh, Christophe & Koper, Ger, 2007. "Influence of the stick-slip transition on the electrokinetic behavior of nanoporous material," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 373(C), pages 21-28.
    • Handle: RePEc:eee:phsmap:v:373:y:2007:i:c:p:21-28
    DOI: 10.1016/j.physa.2006.08.068
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