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Phase transitions and adsorption isotherm in multilayer adsorbates with lateral interactions

Author

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  • Casal, Sonia B
  • Wio, Horacio S
  • Mangioni, S

Abstract

We analyze here a model for an adsorbate system composed of many layers by extending a theoretical approach used to describe pattern formation on a monolayer of adsorbates with lateral interactions. The approach shows, in addition to a first-order phase transition in the first layer, a transition in the second layer together with evidence of a “cascade” of transitions if more layers are included. The transition profiles, showing a staircase structure, corroborate this picture. The adsorption isotherm that came out of this approach is in qualitative agreement with numerical and experimental results.

Suggested Citation

  • Casal, Sonia B & Wio, Horacio S & Mangioni, S, 2002. "Phase transitions and adsorption isotherm in multilayer adsorbates with lateral interactions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 311(3), pages 443-457.
    • Handle: RePEc:eee:phsmap:v:311:y:2002:i:3:p:443-457
    DOI: 10.1016/S0378-4371(02)00828-2
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