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Multi-scaling properties of phase segregation in quenched binary fluids

Author

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  • Martı́nez, G.
  • Gonçalves, S.
  • Iglesias, J.R.

Abstract

The phase separation process in two-dimensional binary fluid systems is investigated using molecular dynamics for almost 20 000 particles. Previous works from the same authors have shown that the late-stage coarsening regime at critical volume fractions is described by power laws whose exponents are dependent on particle–particle interactions and on temperature in a non-universal way. At the low-temperature region, however, the emergence of a three-phase regime of percolating domains with atoms of type-A, type-B and voids, invalidates the single-length scale invariance. We argue in terms of a multiple-length scale analysis. In particular, for the case we studied with symmetric molecular pair potentials we propose two divergent length scales to characterize the dynamic process: one associated to the average size of equal-atom domains and the other related to the average size of undistinguishable-atom domains. Two different growth exponents can be inferred in such a case but the system does not exhibit scale invariance.

Suggested Citation

  • Martı́nez, G. & Gonçalves, S. & Iglesias, J.R., 1998. "Multi-scaling properties of phase segregation in quenched binary fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 257(1), pages 380-384.
  • Handle: RePEc:eee:phsmap:v:257:y:1998:i:1:p:380-384
    DOI: 10.1016/S0378-4371(98)00163-0
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