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Statistical thermodynamics of disperse systems

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  • Shapiro, Alexander A.

Abstract

Principles of statistical physics are applied for the description of thermodynamic equilibrium in disperse systems. The cells of disperse systems are shown to possess a number of non-standard thermodynamic parameters. A random distribution of these parameters in the system is determined. On the basis of this distribution, it is established that the disperse system has an additional degree of freedom called the macro-entropy. A large set of bounded ideal disperse systems allows exact evaluation of thermodynamic characteristics. The theory developed is applied to the description of equilibrium states of a two-phase multicomponent mixture in a porous medium.

Suggested Citation

  • Shapiro, Alexander A., 1996. "Statistical thermodynamics of disperse systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 232(1), pages 499-516.
    • Handle: RePEc:eee:phsmap:v:232:y:1996:i:1:p:499-516
    DOI: 10.1016/0378-4371(96)00137-9
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    1. Akiyama, Yoshiaki, 1969. "行政指導と私人の権利救済 = Verwaltungsleitung und Rechtsschutz," 商学討究 (Shogaku Tokyu), Otaru University of Commerce, vol. 20(2), pages 1-22.
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      Keywords

      Disperse systems; Statistical physics;

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