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Fast dynamics below and around the glass transition in a sidegroup polymer (PVME)

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  • Chahid, A.
  • Colmenero, J.
  • Alegría, A.

Abstract

We have investigated the dynamics of a sidegroup polymer, poly(vinyl methyl ether) (PVME) in the time scale between 10-11 s and 10-13 s by means of time-of-flight quasi-elastic neutron scattering below and around the glass transition Tg. The quasi-elastic broadening of the spectra are interpreted in terms of a local motion of the methyl sidegroups and a model for this motion is presented. Additional scattering appears in the quasi-elastic range at T>Tg. Some preliminary results concerning the dynamics of this system above the glass transition are also reported.

Suggested Citation

  • Chahid, A. & Colmenero, J. & Alegría, A., 1993. "Fast dynamics below and around the glass transition in a sidegroup polymer (PVME)," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 201(1), pages 101-105.
  • Handle: RePEc:eee:phsmap:v:201:y:1993:i:1:p:101-105
    DOI: 10.1016/0378-4371(93)90405-S
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