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A two-layer model of an interface between immiscible fluids

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  • Shikhmurzaev, Y.D.

Abstract

The theory of non-equilibrium thermodynamics and an approach developed by Bedeaux, Albano and Mazur are applied to a system of two immiscible one-component fluids and the interface between them in order to derive a model suitable for the moving contact-line problem analysis. The mass densities of both components at the interface are allowed to be singular in a thermodynamic sense. Some assumptions concerning the interface structure make it possible to obtain a simple mathematical model containing few phenomenological coefficients with clear physical meanings. The model allows to describe the “splitting” of an interface at the moving contact line.

Suggested Citation

  • Shikhmurzaev, Y.D., 1993. "A two-layer model of an interface between immiscible fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 192(1), pages 47-62.
  • Handle: RePEc:eee:phsmap:v:192:y:1993:i:1:p:47-62
    DOI: 10.1016/0378-4371(93)90143-R
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