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A probabilistic analysis of the Walker-Vause model for liquid binary mixtures

Author

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  • Güémez, J.
  • Calvo Hernández, A.
  • Velasco, S.
  • Combariza, E.

Abstract

A simple method to calculate the probability distribution for a binary fluid mixture is presented. The method is applid to the Walker-Vause binary liquid model and different temperature vs composition phase diagrams are obtained. These diagrams are obtained using catastrophe theory methods. Comparison with some experimental data are also discussed and a simplified model leading to closed-loop phase diagrams is considered.

Suggested Citation

  • Güémez, J. & Calvo Hernández, A. & Velasco, S. & Combariza, E., 1988. "A probabilistic analysis of the Walker-Vause model for liquid binary mixtures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 152(3), pages 384-399.
    • Handle: RePEc:eee:phsmap:v:152:y:1988:i:3:p:384-399
    DOI: 10.1016/0378-4371(88)90195-1
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    Cited by:

    1. Güémez, J. & Velasco, S. & Calvo Hernández, A., 1989. "Critical points characterization using probability distributions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 154(3), pages 511-520.
    2. Güémez, J. & Velasco, S. & Calvo Hernández, A., 1989. "Critical points characterization using probability distributions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 156(3), pages 823-834.

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