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Fluid-fluid, fluid-solid and three-phase equilibria in the system helium-hydrogen at pressures up to 75 kbar

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  • Van Den Bergh, L.C.
  • Schouten, J.A.
  • Trappeniers, N.J.

Abstract

The phase diagram of the system helium-hydrogen has been studied, using the diamond anvil cell technique, in a pressure range from 15 to 75 kbar and at temperatures from 110 up to 360 K. The fluid-fluid coexistence surface and, in particular, the position of the critical line has been determined. Good agreement is obtained with earlier work on He-H2 at lower pressures up to 9 kbar (W.B. Streett, Astrophys. J. 186 (1973) 1107). Also the three-phase line solid-fluid-fluid has been determined. The divergency of these lines persists up to the highest pressures and it is shown that the fluid-fluid equilibrium region extends to higher temperatures and higher pressures. Moreover, fluid-solid equilibria were studied and the existence of the predicted solid-solid-fluid equilibrium was confirmed.

Suggested Citation

  • Van Den Bergh, L.C. & Schouten, J.A. & Trappeniers, N.J., 1987. "Fluid-fluid, fluid-solid and three-phase equilibria in the system helium-hydrogen at pressures up to 75 kbar," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 141(2), pages 524-538.
  • Handle: RePEc:eee:phsmap:v:141:y:1987:i:2:p:524-538
    DOI: 10.1016/0378-4371(87)90179-8
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    References listed on IDEAS

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    1. Donald Bogue & Edmund Murphy, 1964. "The effect of classification errors upon statistical inference: A case analysis with census data," Demography, Springer;Population Association of America (PAA), vol. 1(1), pages 42-55, March.
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    Cited by:

    1. Vos, Willem L. & Schouten, Jan A., 1992. "The phase diagram of the binary mixture nitrogen-helium at high pressure," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 182(3), pages 365-387.

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