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Application of the cluster variation method to the hole theory of fluids

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  • Shinomoto, S.
  • Morita, T.

Abstract

The pair approximation of the cluster variation method is applied to the hole theory of classical fluids and the melting transition of the hard-sphere system is discussed. The exact free volume of the hard-sphere molecule is used to make up an effective ‘interaction’ assigned to a cluster which consists of an occupied site by a molecule and its nearest neighbour sites occupied by molecules and holes. This method supplies much improved results compared with those of the molecular-field approximation which corresponds to the site approximation in the cluster variation method.

Suggested Citation

  • Shinomoto, S. & Morita, T., 1984. "Application of the cluster variation method to the hole theory of fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 127(1), pages 141-151.
  • Handle: RePEc:eee:phsmap:v:127:y:1984:i:1:p:141-151
    DOI: 10.1016/0378-4371(84)90124-9
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