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The electric conductivity of stationary and homogeneous electrolytes up to concentrations c ≈ 1 mol/l

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  • Lessner, G.

Abstract

A theory of the electric conductivity in homogeneous and stationary binary electrolytes is developed which is valid up to concentrations c ≈ 1 mol/l. It is based on the stochastic Liouville equation, the linear superposition approximation in the cluster expansion of the 3-particle distribution functions and the hydrodynamical approximation in the expansion of the 2-particle distribution functions by their moments in momentum space. The limiting law in dilute electrolytes is calculated analytically. For hydrous electrolytes the conductivity is calculated numerically up to concentrations c ≈ 1 mol/l. The results are in a very good agreement with experimental data.

Suggested Citation

  • Lessner, G., 1982. "The electric conductivity of stationary and homogeneous electrolytes up to concentrations c ≈ 1 mol/l," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 116(1), pages 272-288.
    • Handle: RePEc:eee:phsmap:v:116:y:1982:i:1:p:272-288
    DOI: 10.1016/0378-4371(82)90244-8
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