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Generalized cluster expansion for real fluids

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  • Iglói, F.
  • Kollár, J.

Abstract

The equation of state and the pair correlation function of a real fluid is expressed in terms of the equation of state and distribution functions of a reference system. The derived general expression makes it possible to obtain power series for the equation of state, both in powers of a “softness” parameter ξ measuring the “amplitude” of the Boltzmann-factor difference and in powers of a formal parameter λ measuring the “amplitude” of the potential difference (high temperature expansion).

Suggested Citation

  • Iglói, F. & Kollár, J., 1982. "Generalized cluster expansion for real fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 113(1), pages 343-349.
    • Handle: RePEc:eee:phsmap:v:113:y:1982:i:1:p:343-349
    DOI: 10.1016/0378-4371(82)90025-5
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