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Non-equilibrium thermodynamics of interfacial systems

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  • Kovac, Jeffrey

Abstract

The theory of non-equilibrium thermodynamics is applied to a system of two immiscible fluids whose molecules possess internal angular momentum (spin) which are separated by an interface. The conservation laws and the Gibbs relation are used to derive the entropy production at the interface. The resulting linear laws relating the fluxes and forces represent boundary conditions on the hydrodynamic equations for the bulk phases. A limiting case is considered and boundary conditions derived by previous authors are obtained.

Suggested Citation

  • Kovac, Jeffrey, 1981. "Non-equilibrium thermodynamics of interfacial systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 107(2), pages 280-298.
    • Handle: RePEc:eee:phsmap:v:107:y:1981:i:2:p:280-298
    DOI: 10.1016/0378-4371(81)90089-3
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    Cited by:

    1. Vanhaelen, Quentin, 2018. "Entropy production, thermodynamic fluxes and transport coefficients of an interface between two electromagnetic fluids with spin," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 506(C), pages 949-968.
    2. Vanhaelen, Q. & Hennenberg, M. & Slavtchev, S. & Weyssow, B., 2010. "Contribution to the dynamics of a deformable interface between two immiscible electromagnetically controllable fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 389(21), pages 5061-5076.

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