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Three-phase absorption heat storage using a low-cost CaCl2/H2O working pair

Author

Listed:
  • Gao, Jintong
  • You, Jinfang
  • Xu, Zhenyuan

Abstract

Absorption heat storage offers a stable and scalable pathway for long-term thermal energy storage, yet its practical deployment is hindered by the limited energy storage density and high capital cost associated with lithium-based working pairs. In this study, we develop a three-phase absorption heat storage system using a low-cost CaCl2/H2O working pair. By introducing crystallization into the working cycle, the system leverages crystal formation to enhance the energy storage density without compromising operational stability. A 25-kW prototype was established to validate the concept, which provided space heating (45–50 °C), hot water supply (63–67 °C), and cooling (12–14 °C) outputs with energy storage densities of 163.5, 151.4, and 113.1 kWh m−3. Meanwhile, the coefficient of performance (COP) was 0.75, 0.73, and 0.60, with auxiliary electrical consumption representing a marginal 4%–6% of total energy demand. By combining multifunctional outputs with high ESD, the proposed system offers a low-cost, scalable route to sustainable thermal management and holds strong promise for large-scale decarbonization of heating and cooling.

Suggested Citation

  • Gao, Jintong & You, Jinfang & Xu, Zhenyuan, 2026. "Three-phase absorption heat storage using a low-cost CaCl2/H2O working pair," Energy, Elsevier, vol. 355(C).
  • Handle: RePEc:eee:energy:v:355:y:2026:i:c:s0360544226013113
    DOI: 10.1016/j.energy.2026.141205
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