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Co-spontaneous combustion of lignite and anthracite: thermal behavior, kinetic characteristics, interaction mechanism

Author

Listed:
  • Zhang, Xun
  • Yu, Chen
  • Lu, Bing
  • Dai, Fengwei
  • Huang, Ge
  • Zhao, Wenting

Abstract

During coal washing and blending, storage, and transportation processes, the mixing of different coal types is prevalent, which elevates the risk of coal spontaneous combustion. Temperature-programmed oxidation experiments were conducted to simulate the low-temperature oxidation process of blended coals with varying mixing ratios. The actual CO and CO2 values differed from the theoretical values by 1210 ppm and 1884 ppm, respectively. The spontaneous combustion propensity of the samples was evaluated based on calculated thermodynamic parameters such as the lower oxygen concentration limit and heat release intensity. The thermal behavior of mixed coal was simulated by STA experiment, and it was found that the combustion characteristic index, heat release intensity and weight loss rate were significantly enhanced. The performance of H5W5 is obvious in the fourth stage, and the mass difference is about 0.64 %. The competitive endothermic of lignite accelerates its own chemical oxidation exothermic, which leads to the accelerated oxidation of anthracite and induces the overall spontaneous combustion. The research results enrich the oxidation characteristics of mixed coal and provide theoretical support for the prevention and control of spontaneous combustion of mixed coal.

Suggested Citation

  • Zhang, Xun & Yu, Chen & Lu, Bing & Dai, Fengwei & Huang, Ge & Zhao, Wenting, 2025. "Co-spontaneous combustion of lignite and anthracite: thermal behavior, kinetic characteristics, interaction mechanism," Energy, Elsevier, vol. 332(C).
  • Handle: RePEc:eee:energy:v:332:y:2025:i:c:s0360544225028294
    DOI: 10.1016/j.energy.2025.137187
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    References listed on IDEAS

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    1. Bai, Gang & Zhou, Zhongjie & Wang, Jue & Tian, Xiangliang & Zhou, Xihua & Li, Xianlin & Chen, Ying, 2023. "Experimental study on damage law of liquid CO2 cyclic freeze–thaw coal," Energy, Elsevier, vol. 284(C).
    2. Zhang, Xun & Zou, Jiahui & Lu, Bing & Huang, Ge & Yu, Chen & Liang, Huimin, 2023. "Experimental study on effect of mudstone on spontaneous combustion of coal," Energy, Elsevier, vol. 285(C).
    3. Jiang, Bingyou & Yu, Chang-Fei & Yuan, Liang & Lu, Kunlun & Tao, Wenhan & Lin, Hanyi & Zhou, Yu, 2023. "Investigation on oxidative pyrolysis characteristics of bituminous coal through thermal analysis and density functional theory," Applied Energy, Elsevier, vol. 349(C).
    4. Liu, Hao & Li, Zenghua & Yang, Yongliang & Miao, Guodong & Li, Purui & Wang, Guoqin & Zhang, Yifan & Hou, Zhenye, 2024. "Role of moisture content in coal oxidation during the spontaneous combustion latency," Energy, Elsevier, vol. 291(C).
    5. Becattini, Viola & Motmans, Thomas & Zappone, Alba & Madonna, Claudio & Haselbacher, Andreas & Steinfeld, Aldo, 2017. "Experimental investigation of the thermal and mechanical stability of rocks for high-temperature thermal-energy storage," Applied Energy, Elsevier, vol. 203(C), pages 373-389.
    6. Zhang, Xun & Liang, Huimin & Lu, Bing & Qiao, Ling & Huang, Ge & Yu, Chen & Zou, Jiahui, 2024. "Correlation and stage change of key groups and thermal effects of spontaneous coal combustion due to long-term ultraviolet illumination," Energy, Elsevier, vol. 293(C).
    7. Xu, Yong-liang & Liu, Ze-jian & Wen, Xing-lin & Wang, Lan-yun & Lv, Zhi-guang & Wu, Jin-dong & Li, Min-jie, 2022. "The cataclysmic characteristics for bituminous-coal oxidation under uniaxial stress based on catastrophe theory," Energy, Elsevier, vol. 248(C).
    8. Pan, Rongkun & Li, Cong & Chao, Jiangkun & Hu, Daimin & Jia, Hailin, 2023. "Thermal properties and microstructural evolution of coal spontaneous combustion," Energy, Elsevier, vol. 262(PA).
    9. Meng, Xianliang & Sun, Jiali & Chu, Ruizhi & Fan, Lulu & Jiang, Xiaofeng & Tang, Ludeng & Zheng, Donglin, 2023. "Effect of active functional groups in coal on the release behavior of small molecule gases during low-temperature oxidation," Energy, Elsevier, vol. 273(C).
    10. Liu, Qiqi & Liu, Chuang & Ma, Jiayu & Liu, Zhenyi & Sun, Lulu, 2024. "Comprehensive evaluation of low-temperature oxidation characteristics of low-rank bituminous coal and oil shale," Energy, Elsevier, vol. 294(C).
    11. Xin, Haihui & Tian, Wenjiang & Zhou, Banghao & Qi, Xu-yao & Li, Jianfeng & Wu, Jinfeng & Wang, De-ming, 2023. "Pore structure evolution and oxidation characteristic change of coal treated with liquid carbon dioxide and liquid nitrogen," Energy, Elsevier, vol. 268(C).
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