IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v157y2018icp503-515.html
   My bibliography  Save this article

Proposed 2nd Law of Thermodynamics: An assertive statement

Author

Listed:
  • Gaggioli, Richard A.

Abstract

Generally, the 2nd Law is stated in negative, passive terms, in a way that says what cannot happen, or what the best possible outcome could be, or what is an inevitable (e.g., inopportune) consequence. Granted, there has been productive usage of the exergy concept, to do ‘2nd Law Analysis’. Granted, there are statements saying that a consequence of every process is the generation of entropy. And there have been many efforts aiming to use an entropy statement to do ‘2nd Law Modeling’ – to predict the path of processes. While there have been specific successes, there are issues. For example, in some instances a success depends upon an extremization that maximizes the entropy generation (or the rate thereof), while in other instances, minimization. Though there may be criteria for determining whether maximization or minimization is appropriate in a particular application, the need for such a criterion points out a weakness. Proposed here is this: Every process is a consequence of a cause, and to assertively predict the path of a process is to determine consequences of a cause. Entropy production is not a cause but only a consequence. The 2nd Law statement to be proposed herein employs a common measure of cause, namely Gibbs' available energy, and how the expenditure of that cause ensues in a process. Therein lies an underlying principle for modeling the process path (whether macro, nano, bio or micro).

Suggested Citation

  • Gaggioli, Richard A., 2018. "Proposed 2nd Law of Thermodynamics: An assertive statement," Energy, Elsevier, vol. 157(C), pages 503-515.
  • Handle: RePEc:eee:energy:v:157:y:2018:i:c:p:503-515
    DOI: 10.1016/j.energy.2018.05.108
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218309344
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2018.05.108?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:157:y:2018:i:c:p:503-515. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.