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Bioinspired design strategies for high-performance Zn-MnO₂ batteries

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  • Bhandari, Ramesh

Abstract

In this review, we explore bioinspired structural approaches that enhance both electrochemical performance and mechanical durability in Zn-MnO₂ batteries. Specifically, we investigate nature-based mass transport methods derived from plant vascular systems and hierarchical porosity structures to optimize Zn2+ ion transport and charge storage efficiency. Additionally, bioinspired mechanical reinforcement strategies—modeled after exoskeletons, honeycomb frameworks, and nacre-like structures—improve battery electrode stability by reducing phase transition-induced cracking and capacity deterioration. This review synthesizes three key strategies for mitigating dendrite growth and interfacial instability, focusing on conductive nanomaterial integration, defect engineering, and self-healing coatings. We highlight recent advancements in biomimetic coating that accelerate ion transport and minimize overpotential losses. Furthermore, we examine bioinspired approaches to overcoming Zn-MnO₂ battery limitations, particularly through the development of hierarchical porous MnO₂ cathodes and mechanically robust Zn anodes. The findings underscore the significant impact of biomimetic designs in extending cycle life, improving energy density, and enhancing safety, thereby positioning Zn-MnO₂ batteries as viable candidates for large-scale energy storage applications.

Suggested Citation

  • Bhandari, Ramesh, 2025. "Bioinspired design strategies for high-performance Zn-MnO₂ batteries," Applied Energy, Elsevier, vol. 393(C).
    • Handle: RePEc:eee:appene:v:393:y:2025:i:c:s0306261925008700
    DOI: 10.1016/j.apenergy.2025.126140
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    1. Jiseok Gim & Noah Schnitzer & Laura M. Otter & Yuchi Cui & Sébastien Motreuil & Frédéric Marin & Stephan E. Wolf & Dorrit E. Jacob & Amit Misra & Robert Hovden, 2019. "Nanoscale deformation mechanics reveal resilience in nacre of Pinna nobilis shell," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    2. Qian Ma & Junhua Zhang, 2023. "Nonlinear Constitutive and Mechanical Properties of an Auxetic Honeycomb Structure," Mathematics, MDPI, vol. 11(9), pages 1-14, April.
    3. Siwon Yu & Seunggyu Park & Kang Taek Lee & Jun Yeon Hwang & Soon Hyung Hong & Thomas James Marrow, 2024. "On the crack resistance and damage tolerance of 3D-printed nature-inspired hierarchical composite architecture," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
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