Two-Dimensional Metal-Organic Frameworks for Agricultural Applications: Novel Copper Coordination Polymer Design

Two-dimensional metal-organic frameworks (2D MOFs) have emerged as promising materials for agricultural applications due to their unique structural properties and tunable functionality. This study focuses on novel copper coordination polymer designs that demonstrate exceptional performance in agricultural enzyme inhibition, particularly targeting urease activity. The development of copper-based 2D coordination polymers with tailored ligand systems has shown remarkable potential for enhancing agricultural productivity through controlled nutrient release and soil stabilization mechanisms. Recent advances in synthetic methodologies have enabled the creation of highly stable copper coordination frameworks that maintain their structural integrity under agricultural conditions while providing sustained inhibitory effects on soil enzymes. The incorporation of auxiliary ligands in copper-based systems has proven particularly effective in modulating the electronic and structural properties of these materials, leading to enhanced performance in agricultural applications. These 2D copper coordination polymers exhibit superior stability compared to traditional enzyme inhibitors and offer environmentally friendly alternatives for modern sustainable agriculture. The multifunctional nature of these materials allows for simultaneous applications in nutrient management, soil conditioning, and crop protection systems. This review examines the latest developments in copper-based 2D MOF synthesis, characterization, and their specific applications in agricultural enzyme inhibition, providing insights into future directions for sustainable agricultural technology development.