IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-44145-7.html
   My bibliography  Save this article

3D microprinting of inorganic porous materials by chemical linking-induced solidification of nanocrystals

Author

Listed:
  • Minju Song

    (Ulsan National Institute of Science and Technology (UNIST))

  • Yoonkyum Kim

    (Ulsan National Institute of Science and Technology (UNIST))

  • Du San Baek

    (Ulsan National Institute of Science and Technology (UNIST))

  • Ho Young Kim

    (Korea Institute of Science and Technology (KIST))

  • Da Hwi Gu

    (Ulsan National Institute of Science and Technology (UNIST))

  • Haiyang Li

    (Pohang University of Science and Technology (POSTECH))

  • Benjamin V. Cunning

    (Institute for Basic Science (IBS))

  • Seong Eun Yang

    (Ulsan National Institute of Science and Technology (UNIST))

  • Seung Hwae Heo

    (Pohang University of Science and Technology (POSTECH))

  • Seunghyun Lee

    (Ulsan National Institute of Science and Technology (UNIST))

  • Minhyuk Kim

    (Ulsan National Institute of Science and Technology (UNIST))

  • June Sung Lim

    (Ulsan National Institute of Science and Technology (UNIST)
    Seoul National University)

  • Hu Young Jeong

    (Ulsan National Institute of Science and Technology (UNIST))

  • Jung-Woo Yoo

    (Ulsan National Institute of Science and Technology (UNIST))

  • Sang Hoon Joo

    (Seoul National University)

  • Rodney S. Ruoff

    (Ulsan National Institute of Science and Technology (UNIST)
    Ulsan National Institute of Science and Technology (UNIST)
    Institute for Basic Science (IBS))

  • Jin Young Kim

    (Korea Institute of Science and Technology (KIST))

  • Jae Sung Son

    (Pohang University of Science and Technology (POSTECH))

Abstract

Three-dimensional (3D) microprinting is considered a next-generation manufacturing process for the production of microscale components; however, the narrow range of suitable materials, which include mainly polymers, is a critical issue that limits the application of this process to functional inorganic materials. Herein, we develop a generalised microscale 3D printing method for the production of purely inorganic nanocrystal-based porous materials. Our process is designed to solidify all-inorganic nanocrystals via immediate dispersibility control and surface linking-induced interconnection in the nonsolvent linker bath and thereby creates multibranched gel networks. The process works with various inorganic materials, including metals, semiconductors, magnets, oxides, and multi-materials, not requiring organic binders or stereolithographic equipment. Filaments with a diameter of sub-10 μm are printed into designed complex 3D microarchitectures, which exhibit full nanocrystal functionality and high specific surface areas as well as hierarchical porous structures. This approach provides the platform technology for designing functional inorganics-based porous materials.

Suggested Citation

  • Minju Song & Yoonkyum Kim & Du San Baek & Ho Young Kim & Da Hwi Gu & Haiyang Li & Benjamin V. Cunning & Seong Eun Yang & Seung Hwae Heo & Seunghyun Lee & Minhyuk Kim & June Sung Lim & Hu Young Jeong &, 2023. "3D microprinting of inorganic porous materials by chemical linking-induced solidification of nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-44145-7
    DOI: 10.1038/s41467-023-44145-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-44145-7
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-44145-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Ok-Hee Kim & Yong-Hun Cho & Soon Hyung Kang & Hee-Young Park & Minhyoung Kim & Ju Wan Lim & Dong Young Chung & Myeong Jae Lee & Heeman Choe & Yung-Eun Sung, 2013. "Ordered macroporous platinum electrode and enhanced mass transfer in fuel cells using inverse opal structure," Nature Communications, Nature, vol. 4(1), pages 1-9, December.
    2. Peter J. Santos & Paul A. Gabrys & Leonardo Z. Zornberg & Margaret S. Lee & Robert J. Macfarlane, 2021. "Macroscopic materials assembled from nanoparticle superlattices," Nature, Nature, vol. 591(7851), pages 586-591, March.
    3. Hye-Eun Lee & Hyo-Yong Ahn & Jungho Mun & Yoon Young Lee & Minkyung Kim & Nam Heon Cho & Kiseok Chang & Wook Sung Kim & Junsuk Rho & Ki Tae Nam, 2018. "Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles," Nature, Nature, vol. 556(7701), pages 360-365, April.
    4. Kui Jiao & Jin Xuan & Qing Du & Zhiming Bao & Biao Xie & Bowen Wang & Yan Zhao & Linhao Fan & Huizhi Wang & Zhongjun Hou & Sen Huo & Nigel P. Brandon & Yan Yin & Michael D. Guiver, 2021. "Designing the next generation of proton-exchange membrane fuel cells," Nature, Nature, vol. 595(7867), pages 361-369, July.
    5. Ryan L. Truby & Jennifer A. Lewis, 2016. "Printing soft matter in three dimensions," Nature, Nature, vol. 540(7633), pages 371-378, December.
    6. Fan Guo & Yanqiu Jiang & Zhen Xu & Youhua Xiao & Bo Fang & Yingjun Liu & Weiwei Gao & Pei Zhao & Hongtao Wang & Chao Gao, 2018. "Highly stretchable carbon aerogels," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    7. Shanyu Zhao & Gilberto Siqueira & Sarka Drdova & David Norris & Christopher Ubert & Anne Bonnin & Sandra Galmarini & Michal Ganobjak & Zhengyuan Pan & Samuel Brunner & Gustav Nyström & Jing Wang & Mat, 2020. "Additive manufacturing of silica aerogels," Nature, Nature, vol. 584(7821), pages 387-392, August.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xiaoyu Zhang & Qi Sun & Xing Liang & Puzhong Gu & Zhenyu Hu & Xiao Yang & Muxiang Liu & Zejun Sun & Jia Huang & Guangming Wu & Guoqing Zu, 2024. "Stretchable and negative-Poisson-ratio porous metamaterials," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    2. Xiaota Cheng & Yi-Tao Liu & Yang Si & Jianyong Yu & Bin Ding, 2022. "Direct synthesis of highly stretchable ceramic nanofibrous aerogels via 3D reaction electrospinning," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Zhang, Yong & He, Shirong & Jiang, Xiaohui & Xiong, Mu & Ye, Yuntao & Yang, Xi, 2023. "Three-dimensional multi-phase simulation of proton exchange membrane fuel cell performance considering constriction straight channel," Energy, Elsevier, vol. 267(C).
    4. Zhang, Xiaoqing & Yang, Jiapei & Ma, Xiao & Zhuge, Weilin & Shuai, Shijin, 2022. "Modelling and analysis on effects of penetration of microporous layer into gas diffusion layer in PEM fuel cells: Focusing on mass transport," Energy, Elsevier, vol. 254(PA).
    5. Yunjie Yang & Minli Bai & Laisuo Su & Jizu Lv & Chengzhi Hu & Linsong Gao & Yang Li & Yubai Li & Yongchen Song, 2022. "One-Dimensional Numerical Simulation of Pt-Co Alloy Catalyst Aging for Proton Exchange Membrane Fuel Cells," Sustainability, MDPI, vol. 14(18), pages 1-23, September.
    6. Huimin He & Xi Wei & Bin Yang & Hongzhen Liu & Mingze Sun & Yanran Li & Aixin Yan & Chuyang Y. Tang & Yuan Lin & Lizhi Xu, 2022. "Ultrastrong and multifunctional aerogels with hyperconnective network of composite polymeric nanofibers," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. Ahmed Mohmed Dafalla & Lin Wei & Bereket Tsegai Habte & Jian Guo & Fangming Jiang, 2022. "Membrane Electrode Assembly Degradation Modeling of Proton Exchange Membrane Fuel Cells: A Review," Energies, MDPI, vol. 15(23), pages 1-26, December.
    8. Venkatesan, Suriya & Mitzel, Jens & Wegner, Karsten & Costa, Remi & Gazdzicki, Pawel & Friedrich, Kaspar Andreas, 2022. "Nanomaterials and films for polymer electrolyte membrane fuel cells and solid oxide cells by flame spray pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    9. Yao, Jing & Wu, Zhen & Wang, Huan & Yang, Fusheng & Xuan, Jin & Xing, Lei & Ren, Jianwei & Zhang, Zaoxiao, 2022. "Design and multi-objective optimization of low-temperature proton exchange membrane fuel cells with efficient water recovery and high electrochemical performance," Applied Energy, Elsevier, vol. 324(C).
    10. Lishan Li & Guandu Yang & Jing Lyu & Zhizhi Sheng & Fengguo Ma & Xuetong Zhang, 2023. "Folk arts-inspired twice-coagulated configuration-editable tough aerogels enabled by transformable gel precursors," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    11. Xia, Zhangxun & Sun, Ruili & Jing, Fenning & Wang, Suli & Sun, Hai & Sun, Gongquan, 2018. "Modeling and optimization of Scaffold-like macroporous electrodes for highly efficient direct methanol fuel cells," Applied Energy, Elsevier, vol. 221(C), pages 239-248.
    12. Baofu Ding & Pengyuan Zeng & Ziyang Huang & Lixin Dai & Tianshu Lan & Hao Xu & Yikun Pan & Yuting Luo & Qiangmin Yu & Hui-Ming Cheng & Bilu Liu, 2022. "A 2D material–based transparent hydrogel with engineerable interference colours," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    13. Li, Yanju & Li, Dongxu & Ma, Zheshu & Zheng, Meng & Lu, Zhanghao & Song, Hanlin & Guo, Xinjia & Shao, Wei, 2022. "Performance analysis and optimization of a novel vehicular power system based on HT-PEMFC integrated methanol steam reforming and ORC," Energy, Elsevier, vol. 257(C).
    14. Li, Xiang & Tang, Fumin & Wang, Qianqian & Li, Bing & Dai, Haifeng & Chang, Guofeng & Zhang, Cunman & Ming, Pingwen, 2023. "Effect of cathode catalyst layer on proton exchange membrane fuel cell performance: Considering the spatially variable distribution," Renewable Energy, Elsevier, vol. 212(C), pages 644-654.
    15. Hoang Nghia Vu & Dinh Hoang Trinh & Dat Truong Le Tri & Sangseok Yu, 2023. "Bypass Configurations of Membrane Humidifiers for Water Management in PEM Fuel Cells," Energies, MDPI, vol. 16(19), pages 1-17, October.
    16. Zhang, Zhuo & Wang, Qi-yao & Bai, Fan & Chen, Li & Tao, Wen-quan, 2023. "Performance simulation and key parameters in-plane distribution analysis of a commercial-size PEMFC," Energy, Elsevier, vol. 263(PC).
    17. Chen, Huicui & Zhang, Ruirui & Xia, Zhifeng & Weng, Qianyao & Zhang, Tong & Pei, Pucheng, 2023. "Experimental investigation on PEM fuel cell flooding mitigation under heavy loading condition," Applied Energy, Elsevier, vol. 349(C).
    18. Bai, Fan & Quan, Hong-Bing & Yin, Ren-Jie & Zhang, Zhuo & Jin, Shu-Qi & He, Pu & Mu, Yu-Tong & Gong, Xiao-Ming & Tao, Wen-Quan, 2022. "Three-dimensional multi-field digital twin technology for proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 324(C).
    19. Yuzhen Xia & Hangwei Lei & Xiaojun Wu & Guilin Hu & Hao Pan & Baizeng Fang, 2023. "Design of New Test System for Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 16(2), pages 1-11, January.
    20. Chi Zhang & Huatian Hu & Chunmiao Ma & Yawen Li & Xujie Wang & Dongyao Li & Artur Movsesyan & Zhiming Wang & Alexander Govorov & Quan Gan & Tao Ding, 2024. "Quantum plasmonics pushes chiral sensing limit to single molecules: a paradigm for chiral biodetections," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-44145-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.