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Remediation of Micro-Pollution in an Alkaline Washing Solution of Fly Ash Using Simulated Exhaust Gas: Parameters and Mechanism

Author

Listed:
  • Lei Wang

    (School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, China
    These authors contributed equally to this work.)

  • Yuemei Tang

    (School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, China
    State Environmental Protection Key Laboratory of Pesticide Environmental Assessment and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Nanjing 210042, China
    These authors contributed equally to this work.)

  • Yu Gong

    (State Environmental Protection Key Laboratory of Pesticide Environmental Assessment and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Nanjing 210042, China)

  • Xiang Shao

    (State Environmental Protection Key Laboratory of Pesticide Environmental Assessment and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Nanjing 210042, China)

  • Xiaochen Lin

    (State Environmental Protection Key Laboratory of Pesticide Environmental Assessment and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Nanjing 210042, China)

  • Weili Xu

    (State Environmental Protection Key Laboratory of Pesticide Environmental Assessment and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Nanjing 210042, China)

  • Yifan Zhu

    (State Environmental Protection Key Laboratory of Pesticide Environmental Assessment and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Nanjing 210042, China)

  • Yongming Ju

    (State Environmental Protection Key Laboratory of Pesticide Environmental Assessment and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Nanjing 210042, China
    The Key Laboratory of Water and Air Pollution Control of Guangdong Province, South China Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Guangzhou 510655, China)

  • Lili Shi

    (State Environmental Protection Key Laboratory of Pesticide Environmental Assessment and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment (MEE), Nanjing 210042, China)

  • Dorota Kołodyńska

    (Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, Maria Curie-Skłodowska Sq. 2, 20-031 Lublin, Poland)

Abstract

Currently, there is an urgent need to remediate heavy metals (HMs) and high alkalinity in the washing solution of fly ash (FA). This study investigated the remediation with simulated exhaust gases of two CO 2 partial pressure and revealed the removal efficiency of target pollutants, mainly including Pb ions. The results verify that under the preferred conditions of 25 °C and 15 mL/min flow rate, bubbling two kinds of simulated flue gases could efficiently remove 97.9–99.2% of Pb ions. Moreover, the initial 40 min removal of Pb ions fits in a way with a pseudo-first-order equation. Based on the thermodynamic parameters, we infer that the removal of Pb ions was a spontaneous, exothermic, and entropy-decreasing process. Furthermore, residual HMs and terminal pH after remediation of the FA washing solution basically met the regulatory threshold values of the integrated wastewater discharge standard in China (GB 8978−1996). Additionally, the particles obtained from the washing solution of FA were identified as CaCO 3 , which was mainly composed of vaterite and calcite crystalline. This study provides a fundamental guide for remediating multiple pollutants in the washing solution of FA and simultaneously sequestrating carbon emissions from power plants and industries.

Suggested Citation

  • Lei Wang & Yuemei Tang & Yu Gong & Xiang Shao & Xiaochen Lin & Weili Xu & Yifan Zhu & Yongming Ju & Lili Shi & Dorota Kołodyńska, 2023. "Remediation of Micro-Pollution in an Alkaline Washing Solution of Fly Ash Using Simulated Exhaust Gas: Parameters and Mechanism," Sustainability, MDPI, vol. 15(7), pages 1-15, March.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:7:p:5873-:d:1109593
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    References listed on IDEAS

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