IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v9y2016i8p611-d75253.html
   My bibliography  Save this article

Environment-Friendly Heterogeneous Alkaline-Based Mixed Metal Oxide Catalysts for Biodiesel Production

Author

Listed:
  • Hwei Voon Lee

    (Nanotechnology & Catalysis Research Centre (NanoCat), Institute of Postgraduate Studies, University Malaya, 50603 Kuala Lumpur, Malaysia)

  • Joon Ching Juan

    (Nanotechnology & Catalysis Research Centre (NanoCat), Institute of Postgraduate Studies, University Malaya, 50603 Kuala Lumpur, Malaysia
    Monash University, Sunway Campus, Jalan Lagoon Selatan, 46150 Sunway Selangor, Malaysia)

  • Taufiq-Yap Yun Hin

    (Catalysis Science and Technology Research Centre (PutraCat), Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia)

  • Hwai Chyuan Ong

    (Department of Mechanical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia)

Abstract

The critical problem arising from the depletion of fossil fuels has stimulated recent interests in alternative sources for petroleum-based fuel. An alternative fuel should be technically feasible, readily available, sustainable, and techno-economically competitive. Biodiesel is considered as a potential replacement of conventional diesel fuel, which is prepared from non-edible and high-acid feedstock via transesterification technology. The focus of this study is to investigate the catalytic activity of mixed metal oxides (MMOs) as catalysts for biodiesel production by using non-edible jatropha oil as feedstock. Various types of MMOs (CaO-MgO, CaO-ZnO, CaO-La 2 O 3 , and MgO-ZnO) were synthesized via a co-precipitation method. In this study, transesterification activities are closely related to the physicochemical properties of catalysts. The presence of different active metals in the binary system greatly influenced the surface area, basicity, and the stability of catalysts. The catalytic activity of MMO catalysts was increased in the order of CaO-ZnO (94% ± 1%) > CaO ~ CaO-MgO ~ CaO-La 2 O 3 (~90% ± 2%) > MgO-ZnO (83% ± 2%) > MgO (64% ± 1%) > ZnO (41% ± 2%) > La 2 O 3 (23% ± 1%). In addition, the MMO catalysts, especially CaO-ZnO, demonstrated high reusability and catalyst stability for four cycles of transesterification reaction of jatropha oil.

Suggested Citation

  • Hwei Voon Lee & Joon Ching Juan & Taufiq-Yap Yun Hin & Hwai Chyuan Ong, 2016. "Environment-Friendly Heterogeneous Alkaline-Based Mixed Metal Oxide Catalysts for Biodiesel Production," Energies, MDPI, vol. 9(8), pages 1-12, August.
    • Handle: RePEc:gam:jeners:v:9:y:2016:i:8:p:611-:d:75253
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/9/8/611/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/9/8/611/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Endalew, Abebe K. & Kiros, Yohannes & Zanzi, Rolando, 2011. "Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)," Energy, Elsevier, vol. 36(5), pages 2693-2700.
    2. Abdolsaeid Ganjehkaviri & Mohammad Nazri Mohd Jaafar & Seyed Ehsan Hosseini & Anas Basri Musthafa, 2016. "Performance Evaluation of Palm Oil-Based Biodiesel Combustion in an Oil Burner," Energies, MDPI, vol. 9(2), pages 1-10, February.
    3. Ruengwit Sawangkeaw & Pornicha Tejvirat & Chawalit Ngamcharassrivichai & Somkiat Ngamprasertsith, 2012. "Supercritical Transesterification of Palm Oil and Hydrated Ethanol in a Fixed Bed Reactor with a CaO/Al 2 O 3 Catalyst," Energies, MDPI, vol. 5(4), pages 1-19, April.
    4. Jain, Siddharth & Sharma, M.P., 2010. "Prospects of biodiesel from Jatropha in India: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 763-771, February.
    5. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    6. Meng, Xin & Yang, Jianming & Xu, Xin & Zhang, Lei & Nie, Qingjuan & Xian, Mo, 2009. "Biodiesel production from oleaginous microorganisms," Renewable Energy, Elsevier, vol. 34(1), pages 1-5.
    7. Lee, H.V. & Taufiq-Yap, Y.H. & Hussein, M.Z. & Yunus, R., 2013. "Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts," Energy, Elsevier, vol. 49(C), pages 12-18.
    8. Xiangzheng Deng & Jianzhi Han & Fang Yin, 2012. "Net Energy, CO 2 Emission and Land-Based Cost-Benefit Analyses of Jatropha Biodiesel: A Case Study of the Panzhihua Region of Sichuan Province in China," Energies, MDPI, vol. 5(7), pages 1-15, June.
    9. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "Production of biodiesel using high free fatty acid feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3275-3285.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Laureano Costarrosa & David Eduardo Leiva-Candia & Antonio José Cubero-Atienza & Juan José Ruiz & M. Pilar Dorado, 2018. "Optimization of the Transesterification of Waste Cooking Oil with Mg-Al Hydrotalcite Using Response Surface Methodology," Energies, MDPI, vol. 11(2), pages 1-9, January.
    2. Hoora Mazaheri & Hwai Chyuan Ong & Zeynab Amini & Haji Hassan Masjuki & M. Mofijur & Chia Hung Su & Irfan Anjum Badruddin & T.M. Yunus Khan, 2021. "An Overview of Biodiesel Production via Calcium Oxide Based Catalysts: Current State and Perspective," Energies, MDPI, vol. 14(13), pages 1-23, July.
    3. Bhatia, Shashi Kant & Bhatia, Ravi Kant & Yang, Yung-Hun, 2017. "An overview of microdiesel — A sustainable future source of renewable energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1078-1090.
    4. Ngee S. Chong & Ifeanyi Nwobodo & Madison Strait & Dakota Cook & Saidi Abdulramoni & Beng G. Ooi, 2023. "Preparation and Characterization of Shell-Based CaO Catalysts for Ultrasonication-Assisted Production of Biodiesel to Reduce Toxicants in Diesel Generator Emissions," Energies, MDPI, vol. 16(14), pages 1-20, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.
    2. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2013. "Ultrasound-assisted transesterification of crude Jatropha oil using cesium doped heteropolyacid catalyst: Interactions between process variables," Energy, Elsevier, vol. 60(C), pages 283-291.
    3. Sánchez, Marcos & Navas, Marisa & Ruggera, José F. & Casella, Mónica L. & Aracil, José & Martínez, Mercedes, 2014. "Biodiesel production optimization using γAl2O3 based catalysts," Energy, Elsevier, vol. 73(C), pages 661-669.
    4. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    5. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    6. Singh, Bhaskar & Guldhe, Abhishek & Rawat, Ismail & Bux, Faizal, 2014. "Towards a sustainable approach for development of biodiesel from plant and microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 216-245.
    7. Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2012. "Biodiesel production from non-edible plant oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3621-3647.
    8. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    9. Navarro-Pineda, Freddy S. & Baz-Rodríguez, Sergio A. & Handler, Robert & Sacramento-Rivero, Julio C., 2016. "Advances on the processing of Jatropha curcas towards a whole-crop biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 247-269.
    10. Yesilyurt, Murat Kadir & Cesur, Cüneyt & Aslan, Volkan & Yilbasi, Zeki, 2020. "The production of biodiesel from safflower (Carthamus tinctorius L.) oil as a potential feedstock and its usage in compression ignition engine: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    11. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "The effects of water on biodiesel production and refining technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3456-3470.
    12. Zhang, X.L. & Yan, S. & Tyagi, R.D. & Surampalli, R.Y., 2013. "Biodiesel production from heterotrophic microalgae through transesterification and nanotechnology application in the production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 216-223.
    13. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    14. Banerjee, Madhuchanda & Dey, Binita & Talukdar, Jayanta & Chandra Kalita, Mohan, 2014. "Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle," Energy, Elsevier, vol. 69(C), pages 695-699.
    15. Silitonga, A.S. & Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Mekhilef, S., 2011. "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3733-3756.
    16. Bhatia, Shashi Kant & Bhatia, Ravi Kant & Yang, Yung-Hun, 2017. "An overview of microdiesel — A sustainable future source of renewable energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1078-1090.
    17. Patel, Alok & Arora, Neha & Mehtani, Juhi & Pruthi, Vikas & Pruthi, Parul A., 2017. "Assessment of fuel properties on the basis of fatty acid profiles of oleaginous yeast for potential biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 604-616.
    18. Borugadda, Venu Babu & Goud, Vaibhav V., 2012. "Biodiesel production from renewable feedstocks: Status and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4763-4784.
    19. Kalam, M.A. & Ahamed, J.U. & Masjuki, H.H., 2012. "Land availability of Jatropha production in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3999-4007.
    20. Qian, Kun & Shen, Xiang & Wang, Yanxin & Gao, Qiang & Ding, Hongwei, 2015. "In-situ transesterification of Jatropha oil over an efficient solid alkali using low leaching component supported on industrial silica gel," Energy, Elsevier, vol. 93(P2), pages 2251-2257.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:9:y:2016:i:8:p:611-:d:75253. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.