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Life Cycle Assessment of New Oxy-Fuels from Biodiesel-Derived Glycerol

Author

Listed:
  • Francesco Asdrubali

    (Inter-University Research Center on Pollution and Environment "Mauro Felli" (CIRIAF), University of Perugia, Via G. Duranti 63, Perugia 06125, Italy)

  • Franco Cotana

    (Inter-University Research Center on Pollution and Environment "Mauro Felli" (CIRIAF), University of Perugia, Via G. Duranti 63, Perugia 06125, Italy)

  • Federico Rossi

    (Inter-University Research Center on Pollution and Environment "Mauro Felli" (CIRIAF), University of Perugia, Via G. Duranti 63, Perugia 06125, Italy)

  • Andrea Presciutti

    (Inter-University Research Center on Pollution and Environment "Mauro Felli" (CIRIAF), University of Perugia, Via G. Duranti 63, Perugia 06125, Italy)

  • Antonella Rotili

    (Inter-University Research Center on Pollution and Environment "Mauro Felli" (CIRIAF), University of Perugia, Via G. Duranti 63, Perugia 06125, Italy)

  • Claudia Guattari

    (Department of Engineering, University of Roma TRE, Via della Vasca Navale 79, Rome 00146, Italy)

Abstract

Biodiesel is obtained by the process of transesterification of vegetable oils and animal fats and crude glycerol is the main by-product of the biodiesel manufacturing chain. As a result glycerol production has rapidly increased in the last decades. This work focuses on the development and the validation of a process to convert biodiesel-derived glycerol into a fuel for internal combustion engines. In order to obtain a higher conversion efficiency it was necessary to convert crude glycerol to tert -butyl ethers by means of an etherification process that was carried out in the laboratory. Then the obtained glycol-ethers mixture (GEM) was blended with a commercial diesel fuel to improve its thermal efficiency. In this paper a life cycle analysis for these GEM/diesel blends was carried out using a Life Cycle Assessment (LCA) methodology, in order to evaluate the environmental impacts of these new oxy-fuels; from GEM production to GEM use as an additive for diesel fuel. The LCA results highlight that the use of these new oxy-fuels in diesel engines can lead to an effective reduction in terms of greenhouse gases emissions throughout the entire life cycle.

Suggested Citation

  • Francesco Asdrubali & Franco Cotana & Federico Rossi & Andrea Presciutti & Antonella Rotili & Claudia Guattari, 2015. "Life Cycle Assessment of New Oxy-Fuels from Biodiesel-Derived Glycerol," Energies, MDPI, vol. 8(3), pages 1-16, February.
  • Handle: RePEc:gam:jeners:v:8:y:2015:i:3:p:1628-1643:d:46209
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    References listed on IDEAS

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    1. Rossi, Federico & Filipponi, Mirko & Castellani, Beatrice, 2012. "Investigation on a novel reactor for gas hydrate production," Applied Energy, Elsevier, vol. 99(C), pages 167-172.
    2. Beatrice, Carlo & Di Blasio, Gabriele & Lazzaro, Maurizio & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco & Asdrubali, Francesco & Baldinelli, Giorgio & Presciutti, Andrea & Fantozzi, Franc, 2013. "Technologies for energetic exploitation of biodiesel chain derived glycerol: Oxy-fuels production by catalytic conversion," Applied Energy, Elsevier, vol. 102(C), pages 63-71.
    3. Cheng Li & Keaton L. Lesnik & Hong Liu, 2013. "Microbial Conversion of Waste Glycerol from Biodiesel Production into Value-Added Products," Energies, MDPI, vol. 6(9), pages 1-30, September.
    4. Lo Giudice Gino Moncada & Francesco Asdrubali & Antonella Rotili, 2013. "Influence of new fac tors on global energy prospects in the medium term: compar ison among the 2010, 2011 and 2012 editions of the IEA?s World Energy Outlook reports," ECONOMICS AND POLICY OF ENERGY AND THE ENVIRONMENT, FrancoAngeli Editore, vol. 2013(3), pages 67-89.
    5. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    6. Antonio Messineo & Roberto Volpe & Francesco Asdrubali, 2012. "Evaluation of Net Energy Obtainable from Combustion of Stabilised Olive Mill By-Products," Energies, MDPI, vol. 5(5), pages 1-14, May.
    7. Beatrice, Carlo & Di Blasio, Gabriele & Guido, Chiara & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco, 2014. "Mixture of glycerol ethers as diesel bio-derivable oxy-fuel: Impact on combustion and emissions of an automotive engine combustion system," Applied Energy, Elsevier, vol. 132(C), pages 236-247.
    8. Malça, João & Freire, Fausto, 2011. "Life-cycle studies of biodiesel in Europe: A review addressing the variability of results and modeling issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 338-351, January.
    9. Renó, Maria Luiza Grillo & Lora, Electo Eduardo Silva & Palacio, José Carlos Escobar & Venturini, Osvaldo José & Buchgeister, Jens & Almazan, Oscar, 2011. "A LCA (life cycle assessment) of the methanol production from sugarcane bagasse," Energy, Elsevier, vol. 36(6), pages 3716-3726.
    10. Rahmat, Norhasyimi & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2010. "Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 987-1000, April.
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    Cited by:

    1. Carlo Andrea Bollino & Francesco Asdrubali & Paolo Polinori & Simona Bigerna & Silvia Micheli & Claudia Guattari & Antonella Rotili, 2017. "A Note on Medium- and Long-Term Global Energy Prospects and Scenarios," Sustainability, MDPI, vol. 9(5), pages 1-25, May.
    2. Emanuele Bonamente & Flavio Scrucca & Francesco Asdrubali & Franco Cotana & Andrea Presciutti, 2015. "The Water Footprint of the Wine Industry: Implementation of an Assessment Methodology and Application to a Case Study," Sustainability, MDPI, vol. 7(9), pages 1-19, September.

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