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Conversion of crude and pure glycerol into derivatives: A feasibility evaluation

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  • Kong, Pei San
  • Aroua, Mohamed Kheireddine
  • Daud, Wan Mohd Ashri Wan

Abstract

The transformation of glycerol to derivatives has been widely investigated because of the demand to enhance the value of crude glycerol produced by biodiesel and oleochemical industries. Intensive research has focused on the conversion of pure glycerol (PG) to different valuable derivatives. Nevertheless, the feasibility of the direct conversion of crude glycerol (CG), which is a waste byproduct of biodiesel production, through chemical processes has been rarely reported because this application is limited by the impurities of CG. Therefore, this review evaluates the feasibility of the direct transformation of CG to value-added derivatives, supplemented with the performance comparison of both PG and CG. This review also demonstrates that the relevant approaches to transform CG into value-added derivatives mainly rely on the following factors: acceptable production cost, advanced process technology, convenient final product separation and purification, excellent product specification, appropriate CG feedstock quality, and minimum catalyst deactivation problem.

Suggested Citation

  • Kong, Pei San & Aroua, Mohamed Kheireddine & Daud, Wan Mohd Ashri Wan, 2016. "Conversion of crude and pure glycerol into derivatives: A feasibility evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 533-555.
    • Handle: RePEc:eee:rensus:v:63:y:2016:i:c:p:533-555
    DOI: 10.1016/j.rser.2016.05.054
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    References listed on IDEAS

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    3. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    4. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    5. Hajjari, Masoumeh & Tabatabaei, Meisam & Aghbashlo, Mortaza & Ghanavati, Hossein, 2017. "A review on the prospects of sustainable biodiesel production: A global scenario with an emphasis on waste-oil biodiesel utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 445-464.
    6. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    7. Tamošiūnas, Andrius & Gimžauskaitė, Dovilė & Uscila, Rolandas & Aikas, Mindaugas, 2019. "Thermal arc plasma gasification of waste glycerol to syngas," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    8. Zhao, Man & Wang, Yanan & Zhou, Wenting & Zhou, Wei & Gong, Zhiwei, 2023. "Co-valorization of crude glycerol and low-cost substrates via oleaginous yeasts to micro-biodiesel: Status and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 180(C).
    9. Chuepeng, Sathaporn & Komintarachat, Cholada, 2018. "Interesterification optimization of waste cooking oil and ethyl acetate over homogeneous catalyst for biofuel production with engine validation," Applied Energy, Elsevier, vol. 232(C), pages 728-739.

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