IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v6y2013i7p3284-3296d26924.html
   My bibliography  Save this article

Catalytic Steam Reforming of Toluene as a Model Compound of Biomass Gasification Tar Using Ni-CeO 2 /SBA-15 Catalysts

Author

Listed:
  • Jun Tao

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Leiqiang Zhao

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Changqing Dong

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Qiang Lu

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Xiaoze Du

    (Key Laboratory of Condition Monitoring and Control for Power Plant Equipment, Ministry of Education, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Erik Dahlquist

    (School of Sustainable Development of Society and Technology, Mälardalen Univeristy, Västerås, SE-721 23, Sweden)

Abstract

Nickel supported on SBA-15 doped with CeO 2 catalysts (Ni-CeO 2 /SBA-15) was prepared, and used for steam reforming of toluene which was selected as a model compound of biomass gasification tar. A fixed-bed lab-scale set was designed and employed to evaluate the catalytic performances of the Ni-CeO 2 /SBA-15 catalysts. Experiments were performed to reveal the effects of several factors on the toluene conversion and product gas composition, including the reaction temperature, steam/carbon (S/C) ratio, and CeO 2 loading content. Moreover, the catalysts were subjected to analysis of their carbon contents after the steam reforming experiments, as well as to test the catalytic stability over a long experimental period. The results indicated that the Ni-CeO 2 /SBA-15 catalysts exhibited promising capabilities on the toluene conversion, anti-coke deposition and catalytic stability. The toluene conversion reached as high as 98.9% at steam reforming temperature of 850 °C and S/C ratio of 3 using the Ni-CeO 2 (3wt%)/SBA-15 catalyst. Negligible coke formation was detected on the used catalyst. The gaseous products mainly consisted of H 2 and CO, together with a little CO 2 and CH 4 .

Suggested Citation

  • Jun Tao & Leiqiang Zhao & Changqing Dong & Qiang Lu & Xiaoze Du & Erik Dahlquist, 2013. "Catalytic Steam Reforming of Toluene as a Model Compound of Biomass Gasification Tar Using Ni-CeO 2 /SBA-15 Catalysts," Energies, MDPI, vol. 6(7), pages 1-13, July.
    • Handle: RePEc:gam:jeners:v:6:y:2013:i:7:p:3284-3296:d:26924
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/6/7/3284/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/6/7/3284/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Devi, Lopamudra & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G. & van Paasen, Sander V.B. & Bergman, Patrick C.A. & Kiel, Jacob H.A., 2005. "Catalytic decomposition of biomass tars: use of dolomite and untreated olivine," Renewable Energy, Elsevier, vol. 30(4), pages 565-587.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Rakesh N, & Dasappa, S., 2018. "A critical assessment of tar generated during biomass gasification - Formation, evaluation, issues and mitigation strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1045-1064.
    2. Zhang, Zhikun & Liu, Lina & Shen, Boxiong & Wu, Chunfei, 2018. "Preparation, modification and development of Ni-based catalysts for catalytic reforming of tar produced from biomass gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 1086-1109.
    3. Duan, Wenjun & Yu, Qingbo & Liu, Junxiang & Wu, Tianwei & Yang, Fan & Qin, Qin, 2016. "Experimental and kinetic study of steam gasification of low-rank coal in molten blast furnace slag," Energy, Elsevier, vol. 111(C), pages 859-868.
    4. Li, Xueqin & Liu, Peng & Lei, Tingzhou & Wu, Youqing & Chen, Wenxuan & Wang, Zhiwei & Shi, Jie & Wu, Shiyong & Li, Yanling & Huang, Sheng, 2022. "Pyrolysis of biomass Tar model compound with various Ni-based catalysts: Influence of promoters characteristics on hydrogen-rich gas formation," Energy, Elsevier, vol. 244(PB).
    5. Oh, Gunung & Park, Seo Yoon & Seo, Myung Won & Kim, Yong Ku & Ra, Ho Won & Lee, Jae-Goo & Yoon, Sang Jun, 2016. "Ni/Ru–Mn/Al2O3 catalysts for steam reforming of toluene as model biomass tar," Renewable Energy, Elsevier, vol. 86(C), pages 841-847.
    6. Vincenzo Palma & Concetta Ruocco & Eugenio Meloni & Antonio Ricca, 2017. "Influence of Catalytic Formulation and Operative Conditions on Coke Deposition over CeO 2 -SiO 2 Based Catalysts for Ethanol Reforming," Energies, MDPI, vol. 10(7), pages 1-13, July.
    7. Gao, Ningbo & Salisu, Jamilu & Quan, Cui & Williams, Paul, 2021. "Modified nickel-based catalysts for improved steam reforming of biomass tar: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    8. No-Kuk Park & Young Jin Lee & Byung Chan Kwon & Tae Jin Lee & Suk Hwan Kang & Bum Ui Hong & Taejin Kim, 2019. "Optimization of Nickel-Based Catalyst Composition and Reaction Conditions for the Prevention of Carbon Deposition in Toluene Reforming," Energies, MDPI, vol. 12(7), pages 1-13, April.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mauerhofer, A.M. & Schmid, J.C. & Benedikt, F. & Fuchs, J. & Müller, S. & Hofbauer, H., 2019. "Dual fluidized bed steam gasification: Change of product gas quality along the reactor height," Energy, Elsevier, vol. 173(C), pages 1256-1272.
    2. Ahmed, A.M.A & Salmiaton, A. & Choong, T.S.Y & Wan Azlina, W.A.K.G., 2015. "Review of kinetic and equilibrium concepts for biomass tar modeling by using Aspen Plus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1623-1644.
    3. Berrueco, C. & Montané, D. & Matas Güell, B. & del Alamo, G., 2014. "Effect of temperature and dolomite on tar formation during gasification of torrefied biomass in a pressurized fluidized bed," Energy, Elsevier, vol. 66(C), pages 849-859.
    4. Marcin Siedlecki & Wiebren De Jong & Adrian H.M. Verkooijen, 2011. "Fluidized Bed Gasification as a Mature And Reliable Technology for the Production of Bio-Syngas and Applied in the Production of Liquid Transportation Fuels—A Review," Energies, MDPI, vol. 4(3), pages 1-46, March.
    5. Ruivo, Luís & Silva, Tiago & Neves, Daniel & Tarelho, Luís & Frade, Jorge, 2023. "Thermodynamic guidelines for improved operation of iron-based catalysts in gasification of biomass," Energy, Elsevier, vol. 268(C).
    6. Di Wu & Heming Dong & Jiyi Luan & Qian Du & Jianmin Gao & Dongdong Feng & Yu Zhang & Ziqi Zhao & Dun Li, 2023. "Reaction Molecular Dynamics Study on the Mechanism of Alkali Metal Sodium at the Initial Stage of Naphthalene Pyrolysis Evolution," Energies, MDPI, vol. 16(17), pages 1-19, August.
    7. Gao, Ningbo & Salisu, Jamilu & Quan, Cui & Williams, Paul, 2021. "Modified nickel-based catalysts for improved steam reforming of biomass tar: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    8. Zhou, Yuguang & Zhang, Zongxi & Zhang, Yixiang & Wang, Yungang & Yu, Yang & Ji, Fang & Ahmad, Riaz & Dong, Renjie, 2016. "A comprehensive review on densified solid biofuel industry in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1412-1428.
    9. Guan, Guoqing & Kaewpanha, Malinee & Hao, Xiaogang & Abudula, Abuliti, 2016. "Catalytic steam reforming of biomass tar: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 450-461.
    10. Chen, Hongfang & Namioka, Tomoaki & Yoshikawa, Kunio, 2011. "Characteristics of tar, NOx precursors and their absorption performance with different scrubbing solvents during the pyrolysis of sewage sludge," Applied Energy, Elsevier, vol. 88(12), pages 5032-5041.
    11. Shen, Yafei & Yoshikawa, Kunio, 2013. "Recent progresses in catalytic tar elimination during biomass gasification or pyrolysis—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 371-392.
    12. Mario Sisinni & Andrea Di Carlo & Enrico Bocci & Andrea Micangeli & Vincenzo Naso, 2013. "Hydrogen-Rich Gas Production by Sorption Enhanced Steam Reforming of Woodgas Containing TAR over a Commercial Ni Catalyst and Calcined Dolomite as CO 2 Sorbent," Energies, MDPI, vol. 6(7), pages 1-15, July.
    13. Zhou, Chunguang & Rosén, Christer & Engvall, Klas, 2016. "Biomass oxygen/steam gasification in a pressurized bubbling fluidized bed: Agglomeration behavior," Applied Energy, Elsevier, vol. 172(C), pages 230-250.
    14. Prashanth Reddy Buchireddy & Devin Peck & Mark Zappi & Ray Mark Bricka, 2021. "Catalytic Hot Gas Cleanup of Biomass Gasification Producer Gas via Steam Reforming Using Nickel-Supported Clay Minerals," Energies, MDPI, vol. 14(7), pages 1-21, March.
    15. Md Tanvir Alam & Se-Won Park & Sang-Yeop Lee & Yean-Ouk Jeong & Anthony De Girolamo & Yong-Chil Seo & Hang Seok Choi, 2020. "Co-Gasification of Treated Solid Recovered Fuel Residue by Using Minerals Bed and Biomass Waste Blends," Energies, MDPI, vol. 13(8), pages 1-16, April.
    16. Cortazar, M. & Lopez, G. & Alvarez, J. & Amutio, M. & Bilbao, J. & Olazar, M., 2018. "Advantages of confining the fountain in a conical spouted bed reactor for biomass steam gasification," Energy, Elsevier, vol. 153(C), pages 455-463.
    17. Ud Din, Zia & Zainal, Z.A., 2016. "Biomass integrated gasification–SOFC systems: Technology overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1356-1376.
    18. Granada, Enrique & Míguez, J.L. & Febrero, Lara & Collazo, Joaquín & Eguía, Pablo, 2013. "Development of an experimental technique for oil recovery during biomass pyrolysis," Renewable Energy, Elsevier, vol. 60(C), pages 179-184.
    19. Shahbaz, Muhammad & yusup, Suzana & Inayat, Abrar & Patrick, David Onoja & Ammar, Muhammad, 2017. "The influence of catalysts in biomass steam gasification and catalytic potential of coal bottom ash in biomass steam gasification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 468-476.
    20. Pongratz, Gernot & Subotić, Vanja & Hochenauer, Christoph & Scharler, Robert & Anca-Couce, Andrés, 2022. "Solid oxide fuel cell operation with biomass gasification product gases: Performance- and carbon deposition risk evaluation via a CFD modelling approach," Energy, Elsevier, vol. 244(PB).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:6:y:2013:i:7:p:3284-3296:d:26924. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.