IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i7p3237-d1115724.html
   My bibliography  Save this article

Kinetics and Structural Optimization of Cobalt-Oxide Honeycomb Structures Based on Thermochemical Heat Storage

Author

Listed:
  • Gang Xiao

    (Key Laboratory of Clean Energy and Carbon Neutrality of Zhejiang Province, Zhejiang University, Hangzhou 310027, China
    State Key Laboratory of Clean Energy Utilization, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China)

  • Zhide Wang

    (Key Laboratory of Clean Energy and Carbon Neutrality of Zhejiang Province, Zhejiang University, Hangzhou 310027, China
    State Key Laboratory of Clean Energy Utilization, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China)

  • Dong Ni

    (College of Control Science and Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China)

  • Peiwang Zhu

    (Key Laboratory of Clean Energy and Carbon Neutrality of Zhejiang Province, Zhejiang University, Hangzhou 310027, China
    State Key Laboratory of Clean Energy Utilization, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China)

Abstract

Thermochemical heat storage is an important solar-heat-storage technology with a high temperature and high energy density, which has attracted increasing attention and research in recent years. The mono-metallic redox pair Co 3 O 4 /CoO realizes heat storage and exothermic process through a reversible redox reaction. Its basic principle is to store energy by heat absorption through a reduction reaction during high-irradiation hours (high temperature) and then release heat through an exothermic-oxidation reaction during low-irradiation hours (low temperature). This paper presents the design of a cobalt-oxide honeycomb structure, which is extruded from pure Co 3 O 4 , a porous media with a high heat-storage density and a high conversion rate. Based on the experimental data, a three-dimensional axisymmetric multi-physics numerical model was developed to simulate the flow, heat transfer, mass transfer, and chemical reaction in the thermochemical heat-storage reactor. Unlike the previous treatment approach of equating chemical reactions with surface reactions, the model in this paper considers the consumption and generation of solids and the diffusion and transfer of oxygen in the porous medium during the reaction process, which brings the simulation results closer to the real values. Finally, the influence of the physical parameters of the honeycomb-structured body on the storage and exothermic process is explored in a wide range. The simulation results show that the physical-parameter settings and structural design of the cobalt-oxide honeycomb structure used in this paper are reasonable, and are conducive to improving its charging/discharging performance.

Suggested Citation

  • Gang Xiao & Zhide Wang & Dong Ni & Peiwang Zhu, 2023. "Kinetics and Structural Optimization of Cobalt-Oxide Honeycomb Structures Based on Thermochemical Heat Storage," Energies, MDPI, vol. 16(7), pages 1-19, April.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:7:p:3237-:d:1115724
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/7/3237/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/7/3237/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Han, Xiangyu & Wang, Liang & Ling, Haoshu & Ge, Zhiwei & Lin, Xipeng & Dai, Xingjian & Chen, Haisheng, 2022. "Critical review of thermochemical energy storage systems based on cobalt, manganese, and copper oxides," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    2. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    3. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Rood, Mark, 2017. "Thermal energy storage systems for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 82-100.
    4. Tescari, S. & Singh, A. & Agrafiotis, C. & de Oliveira, L. & Breuer, S. & Schlögl-Knothe, B. & Roeb, M. & Sattler, C., 2017. "Experimental evaluation of a pilot-scale thermochemical storage system for a concentrated solar power plant," Applied Energy, Elsevier, vol. 189(C), pages 66-75.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Han, Xiangyu & Wang, Liang & Ling, Haoshu & Ge, Zhiwei & Lin, Xipeng & Dai, Xingjian & Chen, Haisheng, 2022. "Critical review of thermochemical energy storage systems based on cobalt, manganese, and copper oxides," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    2. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    3. Chen, Chen & Kong, Mingmin & Zhou, Shuiqing & Sepulveda, Abdon E. & Hong, Hui, 2020. "Energy storage efficiency optimization of methane reforming with CO2 reactors for solar thermochemical energy storage☆," Applied Energy, Elsevier, vol. 266(C).
    4. Imponenti, Luca & Albrecht, Kevin J. & Kharait, Rounak & Sanders, Michael D. & Jackson, Gregory S., 2018. "Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C," Applied Energy, Elsevier, vol. 230(C), pages 1-18.
    5. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    6. Diana Enescu & Gianfranco Chicco & Radu Porumb & George Seritan, 2020. "Thermal Energy Storage for Grid Applications: Current Status and Emerging Trends," Energies, MDPI, vol. 13(2), pages 1-21, January.
    7. Wang, Wei & Shuai, Yong & He, Xibo & Hou, Yicheng & Qiu, Jun & Huang, Yudong, 2023. "Influence of tank-to-particle diameter ratio on thermal storage performance of random packed-bed with spherical macro-encapsulated phase change materials," Energy, Elsevier, vol. 282(C).
    8. Wang, Wei & He, Xibo & Shuai, Yong & Qiu, Jun & Hou, Yicheng & Pan, Qinghui, 2022. "Experimental study on thermal performance of a novel medium-high temperature packed-bed latent heat storage system containing binary nitrate," Applied Energy, Elsevier, vol. 309(C).
    9. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Castelain, Cathy, 2019. "Integration of a thermochemical energy storage system in a Rankine cycle driven by concentrating solar power: Energy and exergy analyses," Energy, Elsevier, vol. 167(C), pages 498-510.
    10. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    11. Peng, Xinyue & Yao, Min & Root, Thatcher W. & Maravelias, Christos T., 2020. "Design and analysis of concentrating solar power plants with fixed-bed reactors for thermochemical energy storage," Applied Energy, Elsevier, vol. 262(C).
    12. Sedighi, Mohammadreza & Padilla, Ricardo Vasquez & Alamdari, Pedram & Lake, Maree & Rose, Andrew & Izadgoshasb, Iman & Taylor, Robert A., 2020. "A novel high-temperature (>700 °C), volumetric receiver with a packed bed of transparent and absorbing spheres," Applied Energy, Elsevier, vol. 264(C).
    13. Fan, Jinyang & Liu, Wei & Jiang, Deyi & Chen, Junchao & Ngaha Tiedeu, William & Chen, Jie & JJK, Deaman, 2018. "Thermodynamic and applicability analysis of a hybrid CAES system using abandoned coal mine in China," Energy, Elsevier, vol. 157(C), pages 31-44.
    14. Guo, Junfei & Liu, Zhan & Du, Zhao & Yu, Jiabang & Yang, Xiaohu & Yan, Jinyue, 2021. "Effect of fin-metal foam structure on thermal energy storage: An experimental study," Renewable Energy, Elsevier, vol. 172(C), pages 57-70.
    15. Hu, Nan & Li, Zi-Rui & Xu, Zhe-Wen & Fan, Li-Wu, 2022. "Rapid charging for latent heat thermal energy storage: A state-of-the-art review of close-contact melting," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    16. Muhammad Suleman Malik & Naveed Iftikhar & Abdul Wadood & Muhammad Omer Khan & Muhammad Usman Asghar & Shahbaz Khan & Tahir Khurshaid & Ki-Chai Kim & Zabdur Rehman & S. Tauqeer ul Islam Rizvi, 2020. "Design and Fabrication of Solar Thermal Energy Storage System Using Potash Alum as a PCM," Energies, MDPI, vol. 13(23), pages 1-16, November.
    17. Delise, T. & Tizzoni, A.C. & Menale, C. & Telling, M.T.F. & Bubbico, R. & Crescenzi, T. & Corsaro, N. & Sau, S. & Licoccia, S., 2020. "Technical and economic analysis of a CSP plant presenting a low freezing ternary mixture as storage and transfer fluid," Applied Energy, Elsevier, vol. 265(C).
    18. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    19. Mostafavi Tehrani, S. Saeed & Shoraka, Yashar & Nithyanandam, Karthik & Taylor, Robert A., 2019. "Shell-and-tube or packed bed thermal energy storage systems integrated with a concentrated solar power: A techno-economic comparison of sensible and latent heat systems," Applied Energy, Elsevier, vol. 238(C), pages 887-910.
    20. Fernández, Angel G. & Gomez-Vidal, Judith & Oró, Eduard & Kruizenga, Alan & Solé, Aran & Cabeza, Luisa F., 2019. "Mainstreaming commercial CSP systems: A technology review," Renewable Energy, Elsevier, vol. 140(C), pages 152-176.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:7:p:3237-:d:1115724. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.