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Synthesis of V 2 O 5 /Single-Walled Carbon Nanotubes Integrated into Nanostructured Composites as Cathode Materials in High Performance Lithium-Ion Batteries

Author

Listed:
  • Nojan Aliahmad

    (Integrated Nanosystems Development Institute (INDI), Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA
    These authors contributed equally to this work.)

  • Pias Kumar Biswas

    (Integrated Nanosystems Development Institute (INDI), Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA
    Department of Mechanical and Energy Engineering, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA
    These authors contributed equally to this work.)

  • Hamid Dalir

    (Integrated Nanosystems Development Institute (INDI), Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA
    Department of Mechanical and Energy Engineering, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA)

  • Mangilal Agarwal

    (Integrated Nanosystems Development Institute (INDI), Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA
    Department of Mechanical and Energy Engineering, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA)

Abstract

Vanadium pentoxide (V 2 O 5 )-anchored single-walled carbon nanotube (SWCNT) composites have been developed through a simple sol–gel process, followed by hydrothermal treatment. The resulting material is suitable for use in flexible ultra-high capacity electrode applications for lithium-ion batteries. The unique combination of V 2 O 5 with 0.2 wt.% of SWCNT offers a highly conductive three-dimensional network. This ultimately alleviates the low lithium-ion intercalation seen in V 2 O 5 itself and facilitates vanadium redox reactions. The integration of SWCNTs into the layered structure of V 2 O 5 leads to a high specific capacity of 390 mAhg −1 at 0.1 C between 1.8 to 3.8 V, which is close to the theoretical capacity of V 2 O 5 (443 mAhg −1 ). In recent research, most of the V 2 O 5 with carbonaceous materials shows higher specific capacity but limited cyclability and poor rate capability. In this work, good cyclability with only 0.3% per cycle degradation during 200 cycles and enhanced rate capability of 178 mAhg −1 at 10 C have been achieved. The excellent electrochemical kinetics during lithiation/delithiation is attributed to the chemical interaction of SWCNTs entrapped between layers of the V 2 O 5 nanostructured network. Proper dispersion of SWCNTs into the V 2 O 5 structure, and its resulting effects, have been validated by SEM, TEM, XPS, XRD, and electrical resistivity measurements. This innovative hybrid material offers a new direction for the large-scale production of high-performance cathode materials for advanced flexible and structural battery applications.

Suggested Citation

  • Nojan Aliahmad & Pias Kumar Biswas & Hamid Dalir & Mangilal Agarwal, 2022. "Synthesis of V 2 O 5 /Single-Walled Carbon Nanotubes Integrated into Nanostructured Composites as Cathode Materials in High Performance Lithium-Ion Batteries," Energies, MDPI, vol. 15(2), pages 1-16, January.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:2:p:552-:d:723780
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    References listed on IDEAS

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    1. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
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