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Reverse Water–Gas Shift Chemical Looping Using a Core–Shell Structured Perovskite Oxygen Carrier

Author

Listed:
  • Minbeom Lee

    (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-Ro, Daejeon 34141, Korea)

  • Yikyeom Kim

    (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-Ro, Daejeon 34141, Korea)

  • Hyun Suk Lim

    (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-Ro, Daejeon 34141, Korea)

  • Ayeong Jo

    (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-Ro, Daejeon 34141, Korea)

  • Dohyung Kang

    (School of Chemical Engineering, Yeungnam University, 280 Daehak-Ro, Gyeongsan 38541, Korea)

  • Jae W. Lee

    (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-Ro, Daejeon 34141, Korea)

Abstract

Reverse water–gas shift chemical looping (RWGS-CL) offers a promising means of converting the greenhouse gas of CO 2 to CO because of its relatively low operating temperatures and high CO selectivity without any side product. This paper introduces a core–shell structured oxygen carrier for RWGS-CL. The prepared oxygen carrier consists of a metal oxide core and perovskite shell, which was confirmed by inductively coupled plasma mass spectroscopy (ICP-MS), XPS, and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) measurements. The perovskite-structured shell of the prepared oxygen carrier facilitates the formation and consumption of oxygen defects in the metal oxide core during H 2 -CO 2 redox looping cycles. As a result, amounts of CO produced per unit weight of the core–shell structured oxygen carriers were higher than that of a simple perovskite oxygen carrier. Of the metal oxide cores tested, CeO 2 , NiO, Co 3 O 4 , and Co 3 O 4 -NiO, La 0.75 Sr 0.25 FeO 3 -encapsulated Co 3 O 4 -NiO was found to be the most promising oxygen carrier for RWGS-CL, because it was most productive in terms of CO production and exhibited long-term stability.

Suggested Citation

  • Minbeom Lee & Yikyeom Kim & Hyun Suk Lim & Ayeong Jo & Dohyung Kang & Jae W. Lee, 2020. "Reverse Water–Gas Shift Chemical Looping Using a Core–Shell Structured Perovskite Oxygen Carrier," Energies, MDPI, vol. 13(20), pages 1-12, October.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:20:p:5324-:d:427212
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    References listed on IDEAS

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    1. Kang, Dohyung & Lim, Hyun Suk & Lee, Minbeom & Lee, Jae W., 2018. "Syngas production on a Ni-enhanced Fe2O3/Al2O3 oxygen carrier via chemical looping partial oxidation with dry reforming of methane," Applied Energy, Elsevier, vol. 211(C), pages 174-186.
    2. Leung, Dennis Y.C. & Caramanna, Giorgio & Maroto-Valer, M. Mercedes, 2014. "An overview of current status of carbon dioxide capture and storage technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 426-443.
    3. Deshmukh, M.K. & Deshmukh, S.S., 2008. "Modeling of hybrid renewable energy systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(1), pages 235-249, January.
    4. Hong-Hua Qiu & Lu-Ge Liu, 2018. "A Study on the Evolution of Carbon Capture and Storage Technology Based on Knowledge Mapping," Energies, MDPI, vol. 11(5), pages 1-25, May.
    5. Ha Jin Kim & Young Nam Chun, 2020. "Conversion of Biogas to Renewable Energy by Microwave Reforming," Energies, MDPI, vol. 13(16), pages 1-11, August.
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    Cited by:

    1. Tomasz Czakiert & Jaroslaw Krzywanski & Anna Zylka & Wojciech Nowak, 2022. "Chemical Looping Combustion: A Brief Overview," Energies, MDPI, vol. 15(4), pages 1-19, February.
    2. Mohsen Fallah Vostakola & Hasan Ozcan & Rami S. El-Emam & Bahman Amini Horri, 2023. "Recent Advances in High-Temperature Steam Electrolysis with Solid Oxide Electrolysers for Green Hydrogen Production," Energies, MDPI, vol. 16(8), pages 1-50, April.

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