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Corrosion of metals and salt hydrates used for thermochemical energy storage

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  • Solé, Aran
  • Miró, Laia
  • Barreneche, Camila
  • Martorell, Ingrid
  • Cabeza, Luisa F.

Abstract

Solar energy can be efficiently used if thermal energy storage systems are accordingly designed to match availability and demand. Thermal energy storage by thermochemical materials (TCM) is very attractive since these materials present a high storage density. Therefore, compact systems can be designed to provide both heating and cooling in dwellings. One of the main drawbacks of the TCM is corrosion with metals in contact. Hence, the objective of this study is to present the obtained results of an immersion corrosion test following ASTM G1 simulating an open TCM reactor, under humidity and temperature defined conditions. Four common metals: copper, aluminum, stainless steel 316, and carbon steel, and five TCM: CaCl2, Na2S, CaO, MgSO4, and MgCl2, were studied. Aluminum and copper show severe corrosion when combined with Na2S, aluminum corrosion is more significant since the specimen was totally destroyed after 3 weeks. Stainless steel 316 is recommended to be used as a metal container material when storing all tested TCM.

Suggested Citation

  • Solé, Aran & Miró, Laia & Barreneche, Camila & Martorell, Ingrid & Cabeza, Luisa F., 2015. "Corrosion of metals and salt hydrates used for thermochemical energy storage," Renewable Energy, Elsevier, vol. 75(C), pages 519-523.
    • Handle: RePEc:eee:renene:v:75:y:2015:i:c:p:519-523
    DOI: 10.1016/j.renene.2014.09.059
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    2. N’Tsoukpoe, Kokouvi Edem & Osterland, Thomas & Opel, Oliver & Ruck, Wolfgang K.L., 2016. "Cascade thermochemical storage with internal condensation heat recovery for better energy and exergy efficiencies," Applied Energy, Elsevier, vol. 181(C), pages 562-574.
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    5. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen & Chen, Zhao-Yang & Li, Gang & Zhang, Yu, 2015. "Investigation into optimization condition of thermal stimulation for hydrate dissociation in the sandy reservoir," Applied Energy, Elsevier, vol. 154(C), pages 995-1003.
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    8. Salviati, Sergio & Carosio, Federico & Cantamessa, Francesco & Medina, Lilian & Berglund, Lars A. & Saracco, Guido & Fina, Alberto, 2020. "Ice-templated nanocellulose porous structure enhances thermochemical storage kinetics in hydrated salt/graphite composites," Renewable Energy, Elsevier, vol. 160(C), pages 698-706.
    9. Vasu, Anusuiah & Hagos, Ftwi Y. & Noor, M.M. & Mamat, R. & Azmi, W.H. & Abdullah, Abdul A. & Ibrahim, Thamir K., 2017. "Corrosion effect of phase change materials in solar thermal energy storage application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 19-33.
    10. Fernández, Angel G. & Fullana, Margalida & Calabrese, Luigi & Palomba, Valeria & Frazzica, Andrea & Cabeza, Luisa F., 2020. "Corrosion assessment of promising hydrated salts as sorption materials for thermal energy storage systems," Renewable Energy, Elsevier, vol. 150(C), pages 428-434.
    11. Wei, Gaosheng & Wang, Gang & Xu, Chao & Ju, Xing & Xing, Lijing & Du, Xiaoze & Yang, Yongping, 2018. "Selection principles and thermophysical properties of high temperature phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1771-1786.
    12. Bennici, Simona & Dutournié, Patrick & Cathalan, Jérémy & Zbair, Mohamed & Nguyen, Minh Hoang & Scuiller, Elliot & Vaulot, Cyril, 2022. "Heat storage: Hydration investigation of MgSO4/active carbon composites, from material development to domestic applications scenarios," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    13. Browne, Maria C. & Boyd, Ellen & McCormack, Sarah J., 2017. "Investigation of the corrosive properties of phase change materials in contact with metals and plastic," Renewable Energy, Elsevier, vol. 108(C), pages 555-568.

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